Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine

Yaxian Yuan; Jianlin Yao; Jun Lu; Yong Zhang; Renao Gu

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Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine

机译：具有手性（S）-2-（二苯基甲醇）-1-（2-吡啶基甲基）吡咯烷的铜（II）配合物的直接电化学合成和晶体结构

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A new chiral binuclear copper(II) complex of (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine (S-dmpmpH) was prepared by direct electrochemical oxidation of Cu electrode in acetonitrile solutions.The final product,Cu_2(S-dmpmp)_2Cl(mu-OH) was crystallized and characterized by microanalysis,Raman spectroscopy together with X-ray crystallographic determinations.

机译：通过在乙腈溶液中直接电化学氧化铜电极，制备了一种新的（S）-2-（二苯基甲醇）-1-（2-吡啶基甲基）吡咯烷（S-dmpmpH）手性双核铜（II）络合物。将Cu_2（S-dmpmp）_2Cl（mu-OH）结晶并通过微分析，拉曼光谱和X射线晶体学测定对其进行表征。

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来源
《Inorganic Chemistry Communications》 |2005年第11期|共4页
作者
Yaxian Yuan; Jianlin Yao; Jun Lu; Yong Zhang; Renao Gu;
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正文语种 eng
中图分类无机化学;
关键词
Chiral ligand; Copper; Direct electrochemical oxidation; Raman spectroscopy;

机译：手性配体铜直接电化学氧化拉曼光谱;

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1. Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine [J] . Yaxian Yuan, Jianlin Yao, Jun Lu, Inorganic Chemistry Communications . 2005,第11期

机译：具有手性（S）-2-（二苯基甲醇）-1-（2-吡啶基甲基）吡咯烷的铜（II）配合物的直接电化学合成和晶体结构
2. Metal chelates of N-(2-pyridylmethyl)iminodiacetate(2-) ion (pmda). Part I. Two mixed-ligand copper(II) complexes of pmda with N,N-chelating bases. Synthesis, crystal structure and properties of H(2)pmda center dot 0.5H(2)O, [Cu(pmda)(pca)]center dot [J] . Choquesillo-Lazarte D., Covelo B., Gonzalez-Perez JM., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第14a15期

机译：N-（2-吡啶基甲基）亚氨基二乙酸酯（2-）离子（pmda）的金属螯合物。第一部分。pmda与N，N螯合碱的两种混合配体铜（II）配合物。 H（2）pmda中心点0.5H（2）O，[Cu（pmda）（pca）]中心点的合成，晶体结构和性质
3. Synthesis and properties of a tetraaza macrocyclic ligand containing 2-pyridylmethyl pendant arms and its copper(II) and nickel(II) complexes: crystal structure of the copper(II) complex [J] . Kang SG., Jeong JH., Kim SJ. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第18期

机译：含2-吡啶基甲基侧链的四氮杂大环配体及其铜（II）和镍（II）配合物的合成与性能：铜（II）配合物的晶体结构
4. Synthesis and Crystal Structure of a Fe(II,III) Complex with 2-(4?-Chlorine-benzoyl)-benzoic Acid and 3-(2-Pyridyl)pyrazole [C] . Qingwei Wang, Ting-Feng Lu, Jia Guo, ICCMME 2012 . 2013

机译：Fe（II，III）络合物的合成和晶体结构，其与2-（4→苯甲酰基） - 苯甲酸和3-（2-吡啶基）吡唑
5. I. THE SYNTHESES, SOLUTION BEHAVIOR, CRYSTAL STRUCTURES AND MAGNETIC PROPERTIES OF SOME IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES. II. THE CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A TRICOPPER(II) CLUSTER CONTAINING A TRIPLY BRIDGING CARBONATE GROUP. [D] . KOLKS, GARY ARNOLD. 1980

机译：I.某些咪唑基桥接铜（II）配合物的合成，溶液行为，晶体结构和磁性。二。含碳桥基的三铜（II）簇的晶体结构和磁性。
6. Crystal structure of a tetranuclear CuII complex with an ONN′-donor Schiff base ligand: hexa-μ2-acetato-bis(2-{(2266-tetramethylpiperidin-4-yl)iminomethyl}phenolato-κ3ONN′)tetracopper(II) [O] . Guohui Huang, Xiaoxuan Liu 2016

机译：具有ONN-施主希夫碱配体的四核CuII配合物的晶体结构：六-μ2-乙酰基-双（2-{（（2266-四甲基哌啶-4-基）亚氨基甲基}酚基-κ3ONN）四铜（II）
7. Synthesis, Crystal Structure, Electrochemical Studies and Artificial Tyrosinase Activity of a New Designed Homobinuclear Copper (II) Complex [O] . Derakhshankhah Hossein, Saboury Ali Akbar, Divsalar Adeleh, 2011

机译：一种新设计的同核双铜（II）配合物的合成，晶体结构，电化学研究和人工酪氨酸酶活性
8. Novel Square Pyramidal Copper(II) Complexes of the Stereospecific Linear NSNNTetradentate Ligand N-((2-Pyridyl)methyl)-2-((2-Aminoethyl)thio) Acetamide (pygeH). The Crystal Structures of (Cu(pyge)X) (X = Br, N3) [R] . Toscano, P. J., Fordon, K. J., Macherone, D., 1990

机译：新型方形金字塔形铜（II）配合物的立体特异性线性NsNN四齿配体N - （（2-吡啶基）甲基）-2 - （（2-氨基乙基）硫代）乙酰胺（pygeH）。（Cu（pyge）X）（X = Br，N3）的晶体结构

Direct electrochemical synthesis and crystal structure of a copper(II) complex with a chiral (S)-2-(diphenylmethanol)-l-(2-pyridylmethyl)pyrrolidine

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