Synthesis,crystal structure and magnetic properties of a new 1D cobalt(II) complex with 1,10-phenanthroline and 3,5-dinitrosalicylate acid ligands

Xin He; Ya-Nan Li; Guang-Hua Li; Ya-Zhuo Li; Ping Zhang

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Synthesis,crystal structure and magnetic properties of a new 1D cobalt(II) complex with 1,10-phenanthroline and 3,5-dinitrosalicylate acid ligands

机译：具有1,10-菲咯啉和3,5-二硝基水杨酸配体的新型一维钴（II）配合物的合成，晶体结构和磁性

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A new cobalt(II) complex,[Co~(II)(phen){3,5-(NO_2)_2sal~(2-)}]_n(1) (3,5-(NO_2)_2sal~(2-) = 3,5-dinitrosalicylate anion,phen = 1,10-phenanthroline),the first cobalt(II) complex with 1,10-phenanthroline and 3,5-dinitrosalicylate acid ligands,has been prepared by hydrothermal synthesis and characterized by single crystal X-ray analysis,IR,XPS spectra,TG-DTA analysis and elemental analysis.This compound displays a linear one-dimensional (1D) chain though cobalt atoms and bridging carboxylate groups of 3,5-dinitrosalicylic acid ligands with Co...Co distance of 4.085 A.Magnetic susceptibility measurements show weak antiferromagnetic interactions in the complexes.

机译：一种新的钴（II）配合物，[Co〜（II）（phen）{3,5-（NO_2）_2sal〜（2-）}] _ n（1）（3,5-（NO_2）_2sal〜（2- ）= 3,5-二硝基水杨酸根阴离子，phen = 1,10-菲咯啉），是第一个具有1,10-菲咯啉和3,5-二硝基水杨酸配位体的钴（II）配合物，是通过水热合成法制备的，并通过单反应进行表征晶体X射线分析，IR，XPS光谱，TG-DTA分析和元素分析。该化合物通过钴原子和3,5-二硝基水杨酸配体与Co的桥接羧酸根基团显示线性一维（1D）链。 Co距离为4.085A。磁化率测量结果表明，配合物中的反铁磁相互作用较弱。

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来源
《Inorganic Chemistry Communications》 |2005年第11期|共5页
作者
Xin He; Ya-Nan Li; Guang-Hua Li; Ya-Zhuo Li; Ping Zhang;
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正文语种 eng
中图分类无机化学;
关键词
Hydrothermal syntheses; Cobalt(II); 3; 5-Dinitrosalicylate acid ligands; Magnetic properties;

机译：水热合成;钴（II）;3;5-二硝基水杨酸配体;磁性;

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1. Synthesis,crystal structure and magnetic properties of a new 1D cobalt(II) complex with 1,10-phenanthroline and 3,5-dinitrosalicylate acid ligands [J] . Xin He, Ya-Nan Li, Guang-Hua Li, Inorganic Chemistry Communications . 2005,第11期

机译：具有1,10-菲咯啉和3,5-二硝基水杨酸配体的新型一维钴（II）配合物的合成，晶体结构和磁性
2. Synthesis, characterization and biological properties of mixed ligand complexes of cobalt(II/III) valproate with 2,9-dimethyl-1,10-phenanthroline and 1,10-phenanthroline [J] . Abu Shamma Amani, Abu Ali Hijazi, Kamel Shayma Applied Organometallic Chemistry . 2018,第1期

机译：用2,9-二甲基-1,10-菲咯啉和1,10菲咯啉的钴（II / III）丙戊糖混合配体复合物的合成，表征及生物学性质
3. Synthesis and crystal structure determination of cobalt(II) mixed-ligand complex containing 1,10-phenanthroline and 5-(2-carboxybenzyloxy)isophthalic acid: Their biological evaluation viz. DNA/protein binding profile, pBR322 DNA cleavage activity [J] . Tabassum Sartaj, Ahmad Musheer, Afzal Mohd, Inorganica Chimica Acta . 2016,第Null期

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4. Synthesis and Crystal Structure of a Cadmium(II) Complex with 2-(4'-Chlorine-benzoyl)-benzoic Acid and 1,10-Phenanthroline [C] . Xiumei Li, Zhitao Wang, Qingwei Wang International Conference on Materials and Products Manufacturing Technology . 2011

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5. Electron-transfer kinetics of copper(II/I) complexes with the ligands 1,10-phenanthroline, 2,2'-bipyridine and their derivatives in acetonitrile. [D] . McGillivary, Michael P. 2006

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Synthesis,crystal structure and magnetic properties of a new 1D cobalt(II) complex with 1,10-phenanthroline and 3,5-dinitrosalicylate acid ligands

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