Solvothermal syntheses and structures of A3AgSn3Se8 (A = Rb,K)

Min Ji; Menghe Baiyin; Shouhua Ji

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Solvothermal syntheses and structures of A3AgSn3Se8 (A = Rb,K)

机译：A3AgSn3Se8的溶剂热合成和结构（A = Rb，K）

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Two new compounds A3AgSn3Se8(A = K,Rb) were synthesized solvothermally and characterized by X-ray single crystal diffraction.These compound are composed of building block [Sn3Se8]~(4-) formed by three edge-sharing SnSe4 tetrahedra,and these building blocks are further connected by tetrahedral coordinated Ag+ to form infinite chains,alkali cations are located between the chains.Their optical properties were also studied.

机译：溶剂热合成了两种新的化合物A3AgSn3Se8（A = K，Rb），并通过X射线单晶衍射对其进行了表征。这些化合物由由三个边缘共享的SnSe4四面体形成的结构单元[Sn3Se8]〜（4-）组成，这些结构单元通过四面体配位的Ag +进一步连接形成无限链，碱金属阳离子位于链之间。还研究了它们的光学性质。

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《Inorganic Chemistry Communications》 |2007年第5期|共3页
作者
Min Ji; Menghe Baiyin; Shouhua Ji;
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正文语种 eng
中图分类无机化学;
关键词
Solvothermal synthesis; Quaternary selenostannate; Chains structure; Optical properties;

机译：溶剂热合成季硒酸锡酸酯链结构光学性质;

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1. Solvothermal syntheses and structures of A3AgSn3Se8 (A = Rb,K) [J] . Min Ji, Menghe Baiyin, Shouhua Ji Inorganic Chemistry Communications . 2007,第5期

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Solvothermal syntheses and structures of A3AgSn3Se8 (A = Rb,K)

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