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Photoluminescence of Ce3+, Pr3+ and Tb3+ activated Sr(3)Ln(PO4)(3) under VUV-UV excitation

机译:在VUV-UV激发下Ce3 +,Pr3 +和Tb3 +激活的Sr(3)Ln(PO4)(3)的光致发光

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摘要

The spectroscopic properties in VUV-Vis range for the eulytite structural phosphors SrGd(PO4)(3):Ln(3+) (Ln(3+) = Ce3+, Pr3+, Tb3+), Sr3C4(PO4)(3), Sr3Gd(PO4)(3) and Sr3Tb(PO4)(3) were investigated. The bands near 170 nm in VUV excitation spectra are assumed to connect with the host lattices related absorption. Thef d transitions of Ce3+, Pr3+ and Tb3+ in the host lattices are assigned and corroborated. A convenient experiment formulation on the relationship between the lowest f-d transition energies and n value for trivalent 4f(n)-series rare earth ions in these host lattices is applied. (C) 2003 Elsevier Inc. All rights reserved. [References: 32]
机译:真绿沸石结构磷光体SrGd(PO4)(3):Ln(3+)(Ln(3+)= Ce3 +,Pr3 +,Tb3 +),Sr3C4(PO4)(3),Sr3Gd(研究了PO4)(3)和Sr3Tb(PO4)(3)。假定在VUV激发光谱中170 nm附近的谱带与基质晶格相关的吸收有关。在主晶格中的Ce3 +,Pr3 +和Tb3 +的fd跃迁被指定和证实。对这些主晶格中三价4f(n)系列稀土离子的最低f-d跃迁能与n值之间的关系进行了方便的实验公式化。 (C)2003 Elsevier Inc.保留所有权利。 [参考:32]

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