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首页> 外文期刊>International Journal of Photoenergy >Photocatalytic Degradation of Rhodamine B Dye over Novel Porous TiO_2-SnO_2 Nanocomposites Prepared by Hydrothermal Method
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Photocatalytic Degradation of Rhodamine B Dye over Novel Porous TiO_2-SnO_2 Nanocomposites Prepared by Hydrothermal Method

机译:水热法制备新型多孔TiO_2-SnO_2纳米复合材料对罗丹明B染料的光催化降解

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摘要

The photocatalytic degradation of Rhodamine B dye was successfully carried out under UV irradiation over porous TiO_2-SnO_2 nanocomposites with various molar ratios of Ti/Sn (4-12) synthesized by hydrothermal method using polystyrene microspheres as template. The combination of TiO_2 with SnO_2 can obtain high quantum yield of TiO_2, and then achieve the high photocatalytic activity. And its porous structure can provide large surface area, leading to more adsorption and fast transfer of dye pollutant. Structural and textural features of the samples were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and N_2 sorption techniques. Both adsorption and UV irradiation contribute to decolorization of about 100% of Rhodamine B dye over the sample TiSn10 after 30 min of the photocatalytic reaction, while the decomposition of Rhodamine B dye is only 62% over pure titania (Degussa P25).
机译:以聚苯乙烯微球为模板,通过水热法合成了不同摩尔比的Ti / Sn(4-12)的多孔TiO_2-SnO_2纳米复合材料,在紫外光下成功地降解了罗丹明B染料。 TiO_2与SnO_2的结合可获得较高的TiO_2量子产率,从而达到较高的光催化活性。而且其多孔结构可以提供较大的表面积,从而导致更多的吸附和染料污染物的快速转移。通过X射线衍射(XRD),透射电子显微镜(TEM)和N_2吸附技术研究了样品的结构和纹理特征。在30分钟的光催化反应后,吸附和紫外线照射都使样品TiSn10上约100%的若丹明B染料脱色,而若丹明B染料的分解仅超过纯二氧化钛(Degussa P25)约62%。

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