Polyhedral azadicarbaborane chemistry. The 'converse' synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes

Dorfler U.; Greatrex R.; Kennedy JD.; Ormsby DL.

首页> 外文期刊>Inorganica Chimica Acta >Polyhedral azadicarbaborane chemistry. The 'converse' synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes

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Polyhedral azadicarbaborane chemistry. The 'converse' synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes

机译：多面性氮杂双偶氮烷化学。少量的6,9-（NHR）-桥联的arachno-5,10-dicarbadecaboranes的“逆向”合成

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Addition of PhC=CH to hypho-type species [(R'H2N)B8H11NHR] proceeds readily with the displacement of R'NH2 to give corresponding N-bridged arachno ten-vertex species [6,9-mu-(NHR)-5-Ph-arachno-5,10-C2B8H10] (15 - 34%), for which DFT structural and GIAO B-11 nuclear shielding calculations suggest the syn configurations that have the R and Ph groupings on the same side of the molecule. (C) 2000 Elsevier Science S.A. All rights reserved. [References: 41]

机译：将PhC = CH添加到疏水型物质[（R'H2N）B8H11NHR]随R'NH2的置换而容易地进行，从而得到相应的N桥键蛛网十顶点种[6,9-mu-（NHR）-5 -Ph-arachno-5,10-C2B8H10]（15-34％），对此，DFT结构和GIAO B-11核屏蔽计算表明该同构构型在分子的同一侧具有R和Ph分组。（C）2000 Elsevier Science S.A.保留所有权利。 [参考：41]

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《Inorganica Chimica Acta》 |2000年第2期|共6页
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Dorfler U.; Greatrex R.; Kennedy JD.; Ormsby DL.;
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正文语种 eng
中图分类生物体其他化学成分;无机化学;
关键词
Boron cluster calculations; Azadicarborane chemistry; Heteroatom incorporation reactions; Nmr chemical-shifts; Magnetic-susceptibilities; Substituted derivatives; Localized quantities; Molecular-structure; Clusters; Terms;

机译：硼团簇计算;氮杂二甲硼烷化学;杂原子结合反应;Nmr化学位移;磁化率;取代的衍生物;局部化数量;分子结构;簇;术语;

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1. Polyhedral azadicarbaborane chemistry. The 'converse' synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes [J] . Dorfler U., Greatrex R., Kennedy JD., Inorganica Chimica Acta . 2000,第2期

机译：多面性氮杂双偶氮烷化学。少量的6,9-（NHR）-桥联的arachno-5,10-dicarbadecaboranes的“逆向”合成
2. Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10](2-) anion to give formally close isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and so [J] . Bown M., Stibr B., Fontaine XLR., Journal of Organometallic Chemistry . 2000,第0期

机译：十一顶点多面体金属ladicarbaborane化学。中性nido-5,6-C2B8H12和[nido-6,9-C2B8H10]（2-）阴离子的反应，形成形式紧密的异构体1-（芳烃）和1-（环戊二烯）-1,2,4-和1,2,3-金属二碳杂十一碳酸酯等
3. Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes. [J] . Macias R, Bould J, Holub J, Dalton transactions: An international journal of inorganic chemistry . 2007,第27期

机译：多面体金属杂硼烷化学。十一顶点{RhNB9}和{PtCB9}金属异杂戊二烯的合成，光谱学，结构和动力学。
4. SYNTHESIS AND CONSTRUCTION OF A FAMILY OF ONE-DOF HIGHLY OVERCONSTRAINED DEPLOYABLE POLYHEDRAL MECHANISMS (DPMS) [C] . Guowu Wei, Jian S Dai ASME international design engineering technical conferences;Computers and information in engineering conference;Mechanisms and robotics conference . 2012

机译：一自由度高度过度约束的多面体机理（DPMS）的合成与构建

Polyhedral azadicarbaborane chemistry. The 'converse' synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes

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