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Dynamical response of borate glasses down to low temperatures

机译:硼酸玻璃在低温下的动态响应

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摘要

Relaxation dynamics of silver ions in the (AgI)_x.(Ag_2O.2B_2O_3)_(1-x) superionic glasses have been studied as a function of temperature between 300 and 90 K in the frequency range from 10~(-3) to 10~9 Hz. The frequency dependent dielectric permittivity has been analysed in terms of conductivity as well as in the formalism of the electric modulus. From the conductivity spectra the Arrhenius dependence of d.c. conductivity as well as the power law exponent characterising the dispersive behaviour at high frequencies have been studied for samples with different AgI content. The analysis of the same data, at fixed frequencies and variable temperatures, in terms of the electrical modulus shows an impressive agreement between the dielectric and the mechanical relaxation process on the (AgI)_(0.6).(Ag_2O.2B_2O_3)_(0.4) glass.
机译:研究了(AgI)_x。(Ag_2O.2B_2O_3)_(1-x)超离子玻璃中银离子的松弛动力学随温度在300〜90 K之间在10〜(-3)到0 10〜9赫兹已经根据电导率以及电模量的形式对频率相关的介电常数进行了分析。从电导率光谱中,直流的阿累尼乌斯依赖性。对于具有不同AgI含量的样品,已经研究了电导率以及表征高频分散行为的幂定律指数。在固定频率和可变温度下对相同数据进行的电模量分析表明,在(AgI)_(0.6)。(Ag_2O.2B_2O_3)_(0.4 )玻璃。

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