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Influence of Both Cooling Rate and TeO_2 Addition on the Properties of YBCO Superconductor

机译:冷却速度和TeO_2添加量对YBCO超导体性能的影响

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Composite of superconducting system YBCO-TeO_2 was synthesized utilizing solid-state reaction technique. Different weight percentages of TeO_2 were mixed with a basic mixture [YBCO] for the synthesis of [YBa_2Cu_3O_(7-y)]_(1-x)(TeO_2)_x composites. These mixtures were sintered at 1213 K (940 °C) for 24 hours and the samples cooled down by two different ways. The first way carried out via slowly cooling in furnace with the rate of 274 K/min to 275 K/min (1 °C/min to 2 °C/min) and the second one is quenching in oxygen gas. The XRD analysis showed that YBCO orthorhombic phase is the major phase appeared in all samples with different TeO_2 content regardless of the cooling way. Additionally, minor unknown secondary phases appeared and enlarged with increasing TeO_2 addition. Although quenched samples showed a phase difference between the sample's outer surface (orthorhombic) and its interior (tetragonal), the slowly cooled one did not clearly show such distinction. Moreover, doping YBCO with TeO_2 leads to increase in the sample bulk density and reduction in their degradation degree in the wet atmosphere.
机译:利用固态反应技术合成了超导体系YBCO-TeO_2的复合材料。将不同重量百分比的TeO_2与碱性混合物[YBCO]混合,以合成[YBa_2Cu_3O_(7-y)] _(1-x)(TeO_2)_x复合材料。将这些混合物在1213 K(940°C)下烧结24小时,然后通过两种不同的方法冷却样品。第一种方法是通过在炉中以274 K / min至275 K / min(1°C / min至2°C / min)的速率缓慢冷却进行,第二种方法是在氧气中淬火。 XRD分析表明,不管冷却方式如何,在所有TeO_2含量不同的样品中,YBCO正交相都是主要相。此外,随着TeO_2添加量的增加,次要的未知次生相出现并扩大。尽管淬火后的样品在样品的外表面(斜方)与内部(四边形)之间显示出相差,但缓慢冷却的样品并没有清楚地显示出这种区别。此外,用TeO_2掺杂YBCO会导致样品体积密度增加,并降低其在潮湿气氛中的降解程度。

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