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首页> 外文期刊>Molecular Crystals and Liquid Crystals Science and Technology, Section A. Molecular Crystals and Liquid Crystals >Monolayers of Poly(#alpha#,#beta#-aspartic acid)with Long Alkyl Chains and Miscibility with L-#alpha#-Phosphatidylcholine at Air-Water Interface
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Monolayers of Poly(#alpha#,#beta#-aspartic acid)with Long Alkyl Chains and Miscibility with L-#alpha#-Phosphatidylcholine at Air-Water Interface

机译:具有长烷基链的聚(#alpha#,#beta#-天冬氨酸)的单分子层,并在空气-水界面与L-#alpha#-磷脂酰胆碱具有互溶性

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摘要

Surface pressure/area isotherms of polypeptides modified with long alkyl chains and their miscibility with DPPC were investigated. The modified polypeptides formed stable monolayers due to their hairy-rod structure and limiting area increased as the degree of substitution increased. Collapse pressure of mixed monolayers deviated from ideal mixture and the free energies of mixing were negative values in all composition.
机译:研究了长烷基链修饰的多肽的表面压力/面积等温线及其与DPPC的相容性。修饰的多肽由于其有毛杆结构而形成稳定的单分子层,并且随着取代度的增加,限制区域增加。混合单层的坍塌压力偏离理想混合物,并且混合的自由能在所有组成中均为负值。

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