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Low-temperature chemical solution route for ZnO based sulfide coaxial nanocables: general synthesis and gas sensor application - art. no. 115619

机译:ZnO基硫化物同轴纳米电缆的低温化学溶液路线:一般合成和气体传感器应用-艺术。没有。 115619

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摘要

A novel chemical solution approach has been developed to synthesize ZnO based sulfide coaxial nanocables such as ZnO/ZnS and ZnO/CdS by chemical reaction in tetrahydrofuran (THF; C4H8O), in which sulfur, NaBH4 and ZnCl2 or CdCl2 were used as reactants and ZnO nanorods were used as the template at room temperature. The morphology and structure of ZnO/ZnS and ZnO/ CdS coaxial nanocables have been characterized by transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), x-ray powder diffraction (XRD), x-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller (BET) analysis. Furthermore, the as-prepared ZnO/ CdS coaxial nanocables have been applied as NH3 gas sensors at room temperature with superior sensitivity, good reproducibility and a short response/recovery time. Finally, a first explanation for the improved performance of the ZnO/CdS coaxial nanocable based gas sensors has been presented.
机译:通过在四氢呋喃(THF; C4H8O)中进行化学反应,开发了一种新的化学溶液方法来合成ZnO基硫化物同轴纳米电缆,如ZnO / ZnS和ZnO / CdS,其中硫,NaBH4和ZnCl2或CdCl2被用作反应物,而ZnO在室温下将纳米棒用作模板。 ZnO / ZnS和ZnO / CdS同轴纳米电缆的形貌和结构已通过透射电子显微镜(TEM),场发射扫描电子显微镜(FESEM),X射线粉末衍射(XRD),X射线光电子能谱(XPS)进行了表征)和Brunauer-Emmett-Teller(BET)分析。此外,所制备的ZnO / CdS同轴纳米电缆已在室温下用作NH3气体传感器,具有优异的灵敏度,良好的可重复性和较短的响应/恢复时间。最后,提出了基于ZnO / CdS同轴纳米电缆的气体传感器性能改善的第一个解释。

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