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首页> 外文期刊>Nanotechnologies in Russia >The formation and luminescent properties of hybrid associates of colloidal Ag2S quantum dots with J-aggregates of trimethinecyanine dye
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The formation and luminescent properties of hybrid associates of colloidal Ag2S quantum dots with J-aggregates of trimethinecyanine dye

机译:胶体Ag2S量子点与三甲花菁染料J聚集体杂合体的形成和发光性质

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摘要

Spectral patterns of hybrid association in the mixture of colloidal Ag_2S quantum dots (QDs) with an average size of 2.5 to 0.3 nm with J-aggregates of a pyridinium salt of 3,3-di(-sulphopropyl)-9-ethyl-4,5,4,5-dibenzothiacarbocyanine betaine (Dye), prepared by the sol-gel method in gelatin, are investigated. A conclusion about the preferential formation of cis-J-aggregates in the hybrid associates of Dye with Ag_2S QDs is made. The effect of photosensitization of IR luminescence (1000C1300 nm) of colloidal Ag_2S QDs by J-aggregates of Dye is revealed. On the basis of the results, a photosensitization scheme implying the resonance nonradiative transfer of the electronic excitation energy from cis-J-aggregates to the recombination luminescence centers of Ag_2S QDs is suggested.
机译:平均大小为2.5至0.3 nm的胶体Ag_2S量子点(QD)与3,3-二(-磺丙基)-9-乙基-4吡啶鎓盐的J聚集体的混合缔合的光谱图研究了通过溶胶-凝胶法在明胶中制备的5,4,5-二苯并硫杂碳菁甜菜碱(Dye)。得出关于染料与Ag_2S QDs杂合体中顺式-J-聚集体优先形成的结论。揭示了染料J聚集体对胶体Ag_2S QDs的IR发光(1000C1300 nm)的光敏作用。根据结果​​,提出了一种光敏化方案,该方案暗示了电子激发能从顺式-J-聚集体到Ag_2S QDs的重组发光中心的共振非辐射转移。

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