New phosphorus self-assembling ligands for the tandem hydroformylation-Wittig olefination reaction of homoallylic alcohols — A key step for stereoselective pyran synthesis

Qiao Ruan; Le Zhou; Bernhard Breit

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New phosphorus self-assembling ligands for the tandem hydroformylation-Wittig olefination reaction of homoallylic alcohols — A key step for stereoselective pyran synthesis

机译：均丙醇的串联加氢甲酰化-Wittig烯化反应的新型磷自组装配体—立体选择性吡喃合成的关键步骤

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摘要

New self-assembled phosphorus ligands are synthesized and used in the rhodium complex catalyzed hydroformylation-Wittig reaction of homoallylic olefins under optimized condition. A subsequent oxa-Michael intramolecular reaction yields (3-pyran derivatives (conversion and diastereoselectivity up to 99%).

机译：合成了新的自组装磷配体，并在优化条件下将其用于铑配合物催化均烯丙基烯烃的加氢甲酰化-Wittig反应。随后的oxa-Michael分子内反应产生（3-吡喃衍生物（转化率和非对映选择性高达99％）。

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《Catalysis Communications》 |2014年第null期|共4页
作者
Qiao Ruan; Le Zhou; Bernhard Breit;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Phosphorus self-assembling ligand; Homoallylic olefin; Wittig reagent; Hydroformylation-Wittig reaction; Oxa-Michael reaction; β-Pyran;

机译：磷自组装配体;烯丙基烯烃;Wittig试剂;加氢甲酰化-Wittig反应;Oxa-Michael反应;β-吡喃;

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1. New phosphorus self-assembling ligands for the tandem hydroformylation-Wittig olefination reaction of homoallylic alcohols — A key step for stereoselective pyran synthesis [J] . Qiao Ruan, Le Zhou, Bernhard Breit Catalysis Communications . 2014,第Null期

机译：均丙醇的串联加氢甲酰化-Wittig烯化反应的新型磷自组装配体—立体选择性吡喃合成的关键步骤
2. Tin- and Indium-Mediated Allylation Reactions in Water: Highly Stereoselective Synthesis of #beta#-Trifluoromethylated Homoallylic Alcohols [J] . Teck-Peng Loh, Xu-Ran Li European journal of organic chemistry . 1999,第8期

机译：锡和铟介导的水中烯丙基化反应：＃β＃-三氟甲基化均烯丙基醇的高度立体选择性合成
3. Gallium-mediated allyl transfer from bulky homoallylic alcohol to aldehydes via retro-allylation: Stereoselective synthesis of both erythro- and threo-homoallylic alcohols [J] . Hayashi S, Hirano K, Yorimitsu H, Organic letters . 2005,第16期

机译：镓介导的烯丙基通过逆向烯丙基化从庞大的均烯丙醇转移至醛类：立体和顺式均丁烯醇的立体选择性合成
4. Stereoselective Synthesis of δ-Silyl-Substituted anti-Homoallylic Alcohols Using Palladium-Catalyzed Three-Component Reaction [C] . MURAKAMI Miki, HORINO Yoshikazu, ABE Hitoshi 日本化学会春季年会講演予稿集 . 2018

机译：使用钯催化的三组分反应的δ-甲硅烷基取代的抗官能醇的立体选择性合成
5. Silylene Transfer: New Silylene-Mediated Multi-Step Reactions for Stereoselective Synthesis and the Development of a New Diarylsilylene Transfer Reagent. [D] . Buchner, Kay Michelle. 2011

机译：甲硅烷基转移：用于立体选择性合成的新甲硅烷基介导的多步反应和新型二芳基甲硅烷基转移试剂的开发。
6. A One-Pot Tandem Strategy in Catalytic Asymmetric Vinylogous Aldol Reaction of Homoallylic Alcohols [O] . Xufeng Hou, Zhenzhong Jing, Xiangbin Bai, 2016

机译：一锅串联策略在不对称乙烯基醇醛醇缩合反应中
7. Determination of the Origin of Stereoselectivity in Multiple-Transition-State Reactions Using DFT Calculations: Enantioselective Synthesis of Homoallylic Alcohols from Aliphatic Methyl Ketones via an Auxiliary-Mediated Allylation [O] . -1

机译：使用DFT计算测定多转过渡态反应中立体选择性的起源：通过辅助介导的烯丙基化对脂族甲基酮的致原性醇的对致映选择性合成

New phosphorus self-assembling ligands for the tandem hydroformylation-Wittig olefination reaction of homoallylic alcohols — A key step for stereoselective pyran synthesis

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