First reusable ligand-free palladium catalyzed C-P bond formation of aryl halides with trialkylphosphites in neat water

Iranpoor Nasser; Firouzabadi Habib; Moghadam Khashayar Rajabi; Motavalli Somayeh

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First reusable ligand-free palladium catalyzed C-P bond formation of aryl halides with trialkylphosphites in neat water

机译：首次在纯水中可重复使用的不含配体的钯催化芳基卤化物与亚磷酸三烷基酯的C-P键形成

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A reusable ligand-free palladium catalyzed phosphonation of aryl iodides, bromides and chlorides with trialkylphosphites is described for the first time in neat water. The aryl phosphonates are obtained in good to excellent yields. The reaction can be also performed with Ni(II) with longer reaction time. The role of tetrabutylammonium bromide in this reaction as reducing agent for generation of Pd(0) at room temperature is also demonstrated. Pd(0)/TBAB was easily reused for three runs without decreasing the efficiency.

机译：首次在纯净水中描述了可重用的无配体的钯催化的芳基碘，溴化物和氯化物与亚磷酸三烷基酯的膦酸化反应。以良好至优异的产率获得芳基膦酸酯。该反应还可以用Ni（II）以更长的反应时间进行。还证明了溴化四丁铵在该反应中作为还原剂的作用，该还原剂在室温下可生成Pd（0）。 Pd（0）/ TBAB可以轻松地重复使用三轮，而不会降低效率。

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《RSC Advances》 |2014年第99期|共6页
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Iranpoor Nasser; Firouzabadi Habib; Moghadam Khashayar Rajabi; Motavalli Somayeh;
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正文语种 eng
中图分类化学;
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1. First reusable ligand-free palladium catalyzed C-P bond formation of aryl halides with trialkylphosphites in neat water [J] . Iranpoor Nasser, Firouzabadi Habib, Moghadam Khashayar Rajabi, RSC Advances . 2014,第99期

机译：首次在纯水中可重复使用的不含配体的钯催化芳基卤化物与亚磷酸三烷基酯的C-P键形成
2. Reusable and Ligand-Free Palladium-Catalyzed Suzuki- Miyaura Cross-Couplings of Aryl Halides with Arylboronic Acids in Tetra-n-butylammonium Bromide [J] . XIE,Ye-Xiang, WANG,Jian, LI,Jin-Heng, 中国化学（英文版） . 2008,第012期
3. Ligand-Free, Palladium-Catalyzed Dihydrogen Generation from TMDS: Dehalogenation of Aryl Halides on Water [J] . Bhattacharjya Anish, Klumphu Piyatida, Lipshutz Bruce H. Organic letters . 2015,第5期

机译：TMDS产生的无配体，钯催化的二氢：芳基卤化物在水中的脱卤
4. Palladium-Catalyzed Cross-Coupling Reaction of Triallyl(aryl)silanes with Aryl Halides [C] . Akhila K.Sahoo, Takuro Oda, Yoshiaki Nakao, Symposium on Organometallic Chemistry . 2003

机译：用芳基卤化物的三叔锭（芳基）硅烷的钯催化的交联反应
5. Part I: The Study of 2-Aryl-1,3-Dithiane Derivatives As Pronucleophiles in Palladium-Catalyzed Allylic Alkylation and Propellylation Part II: Ligand-Free Palladium-Catalyzed Allylic Amintion of Hydrazone Derivatives Part III: Synthesis of Criegee Intermed [D] . Trongsiriwat, Nisalak. 2019

机译：第一部分：将2-芳基-1,3-二硫醚衍生物的研究作为钯催化的烯丙基烷基化和预选型第II部分：腙衍生物的配体钯催化烯丙基胺部分III：Criaegee中间的合成
6. A palladium-catalyzed synthesis of (hetero)aryl-substituted imidazoles from aryl halides imines and carbon monoxide [O] . Jevgenijs Tjutrins, Bruce A. Arndtsen 2017

机译：由芳基卤化物亚胺和一氧化碳钯催化合成（杂）芳基取代的咪唑
7. Palladium-catalyzed C-O bond formation : direct synthesis of phenols and aryl/alkyl ethers from activated aryl halides [O] . Chen G, Chan ASC, Kwong FY 2007

机译：钯催化的C-O键形成：由活化的芳基卤化物直接合成苯酚和芳基/烷基醚

First reusable ligand-free palladium catalyzed C-P bond formation of aryl halides with trialkylphosphites in neat water

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