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Large-scale synthesis and characterization of super-bundle single-walled carbon nanotubes by water-assisted chemical vapor deposition

机译:水辅助化学气相沉积法大规模合成超束单壁碳纳米管及其表征

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A large-scale synthesis of water-assisted single-walled carbon nanotubes (SWCNTs) was investigated over Fe-Mo/MgO catalysts by catalytic chemical vapor deposition of ethylene. Introduction of water vapor into a reactor induced super-bundle SWCNTs (SB-SWCNTs) and dramatically improved the product yield of SWCNTs from 40 to 206 wt%. By adding water vapor, the average diameter of the SB-SWCNTs was increased from 1.5 to 3.0 nm and distribution of the diameter became wider. The Raman peak intensity ratio (I-G/I-D) of the SWCNTs, which indicates the crystallinity and defect degree of SWCNTs, showed an almost constant value of 8 regardless of water vapor concentration. The possible growth mechanism of SB-SWCNTs was discussed.
机译:在Fe-Mo / MgO催化剂上,通过乙烯的催化化学气相沉积,研究了水辅助单壁碳纳米管(SWCNT)的大规模合成。将水蒸气引入反应器中引起的超束SWCNT(SB-SWCNT),并将SWCNT的产物产率从40重量%提高至206重量%。通过添加水蒸气,SB-SWCNT的平均直径从1.5nm增加到3.0nm,并且直径的分布变宽。 SWCNT的拉曼峰强度比(I-G / I-D)表示SWCNT的结晶度和缺陷程度,无论水蒸气浓度如何,其拉曼峰强度比几乎都为8。讨论了SB-SWCNTs可能的生长机理。

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