Synthesis and diverse general oxidative cyclization catalysis of high-valent (MoO2)-O-VI(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity

Pramanik Nabyendu; Sarkar Satinath; Roy Dipanwita; Debnath Sudipto; Ghosh Sukla; Khamarui Saikat; Maiti Dilip K.

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Synthesis and diverse general oxidative cyclization catalysis of high-valent (MoO2)-O-VI(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity

机译：高价（MoO2）-O-VI（HL）到高价杂环及其手性类似物的合成和多种多样的通用氧化环催化

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The first synthesis and diverse oxidative cyclization catalysis properties of high-valent Mo-VI-triazole are demonstrated towards highly selective construction of benzimidazoles, benzothiazoles, isoxazolines, isoxazoles and their chiral analogues.

机译：高价Mo-VI-三唑的首次合成和多样的氧化环化催化性能已证明可对苯并咪唑，苯并噻唑，异恶唑啉，异恶唑及其手性类似物进行高选择性构建。

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《RSC Advances》 |2015年第123期|共6页
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Pramanik Nabyendu; Sarkar Satinath; Roy Dipanwita; Debnath Sudipto; Ghosh Sukla; Khamarui Saikat; Maiti Dilip K.;
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中图分类化学;
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1. Synthesis and diverse general oxidative cyclization catalysis of high-valent (MoO2)-O-VI(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity [J] . Pramanik Nabyendu, Sarkar Satinath, Roy Dipanwita, RSC Advances . 2015,第123期

机译：高价（MoO2）-O-VI（HL）到高价杂环及其手性类似物的合成和多种多样的通用氧化环催化
2. Gold(I) Catalysis: Selective Synthesis of Six- or Seven-Membered Heterocycles from Epoxy Alkynes [J] . Lun-Zhi Dai, Min Shi European journal of organic chemistry . 2009,第19期

机译：金（I）催化：从环氧炔烃选择性合成六元或七元杂环。
3. An enantioselective entry to substituted 6-membered nitrogen heterocycles from chiral pyridinium salts via selective epoxidation of tetrahydropyridine intermediates [J] . Gil L., Guilloteau-Bertin B., Chiaroni A., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2000,第14期

机译：通过四氢吡啶中间体的选择性环氧化，从手性吡啶鎓盐中取代的6-元氮杂环对映体选择性进入
4. Asymmetric Catalysis with “Planar-Chiral” Heterocycles [C] . Gregory C. Fu International symposium for Chinese organic chemists . 2000

机译：与“平面手性”杂环的不对称催化
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。
6. Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles [O] . Nicholas J. Race, *, Ian R. Hazelden, 2017

机译：氮杂-Heck环化用于合成手性N-杂环的最新进展
7. One-Pot-Condensation Reaction of Heterocyclic Amine, 1,3-Diketone and Aldehydes Using In Situ Generated Superoxide Ion: A Rapid Synthesis of Structurally Diverse Drug-Like Complex Heterocycles [O] . Sundaram Singh, Savita Kumari 2020

机译：杂环胺，1,3-二酮和醛的一锅冷凝反应使用原位产生的超氧化离子：在结构上不同的药物状复合物杂环的快速合成

Synthesis and diverse general oxidative cyclization catalysis of high-valent (MoO2)-O-VI(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity

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