One pot hydroamination/[4+3] cycloaddition: synthesis towards the cyclohepta[b]indole core of silicine and ervatamine

Zhang Jie; Shao Jidong; Xue Jijun; Wang Yongxiang; Li Ying

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One pot hydroamination/[4+3] cycloaddition: synthesis towards the cyclohepta[b]indole core of silicine and ervatamine

机译：一锅加氢胺化/ [4 + 3]环加成反应：合成有机硅和麦角胺的环庚[b]吲哚核

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A new and facile tandem reaction of intramolecular hydroamination and novel [4 + 3] cycloaddition was developed for the synthesis of multitudinal indole-containing 5,7,6-tricyclic skeletons. This method was further extended to the quick synthesis of a series of useful motif of natural products, such as the core of ervatamine and silicine.

机译：一个新的和容易的串联反应的分子内氢化和新型[4 + 3]环加成反应被开发用于合成多十二烷基吲哚含5,7,6-三环骨架。该方法进一步扩展为快速合成一系列天然产物的有用基序，例如艾维他命和硅酮的核心。

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《RSC Advances》 |2014年第109期|共5页
作者
Zhang Jie; Shao Jidong; Xue Jijun; Wang Yongxiang; Li Ying;
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正文语种 eng
中图分类化学;
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1. One pot hydroamination/[4+3] cycloaddition: synthesis towards the cyclohepta[b]indole core of silicine and ervatamine [J] . Zhang Jie, Shao Jidong, Xue Jijun, RSC Advances . 2014,第109期

机译：一锅加氢胺化/ [4 + 3]环加成反应：合成有机硅和麦角胺的环庚[b]吲哚核
2. Rhodium-and Platinum-Catalyzed [4+3] Cycloaddition with Concomitant Indole Annulations Synthesis of Cyclohepta[b]indoles [J] . Dongxu Shu, Wangze Song, Xiaoxun Li Angewandte Chemie . 2013,第11期

机译：铑和铂催化的[4 + 3]环加成并伴随吲哚环化合成环庚[b]吲哚
3. Highly Diastereo- and Enantioselective Synthesis of Cyclohepta[b]-indoles by Chiral-Phosphoric-Acid-Catalyzed (4+3) Cycloaddition [J] . Gelis Coralie, Levitre Guillaume, Merad Jeremy, Angewandte Chemie . 2018,第37期

机译：通过手性磷酸 - 催化（4 + 3）环加入的高度自对映异细胞和对致密的环庚基[B]吲哚（4 + 3）
4. One-Pot Synthesis of Indole Derivatives Using Homogeneous and Polymer-Supported Heterogeneous Palladium Catalysts [C] . Ken Tsutsumi, Hayato Sakai, Tsumoru Morimoto Symposium on Organometallic Chemistry . 2006

机译：使用均相和聚合物负载的非均相钯催化剂单罐合成吲哚衍生物
5. Recent advances in indole aryne cycloaddition chemistry. Part I: Total synthesis of (+/-)-cis-trikentrin B. Part II: Investigation into the regioselectivity of 6,7-indole aryne cycloadditions. Part III: Synthesis and reactions of novel tribromoindoles. [D] . Nerurkar, Alok. 2015

机译：吲哚芳烃环加成化学的最新进展。第一部分：（+/-）-顺式trikentrin B的全合成。第二部分：6,7-吲哚亚芳基环加成反应的区域选择性研究。第三部分：新型三溴吲哚的合成与反应。
6. Rhodium- and Platinum-Catalyzed 4+3 Cycloaddition with Concomitant Indole Annulation: Synthesis of Cycloheptabindoles [O] . Dongxu Shu, Wangze Song, Xiaoxun Li, -1

机译：具有伴随吲哚支管的铑和铂催化4 + 3环加成：Cyclohepta的合成B吲哚
7. Rhodium- and Platinum-Catalyzed 4+3 Cycloaddition with Concomitant Indole Annulation: Synthesis of Cycloheptabindoles [O] . Dongxu Shu, Wangze Song, Xiaoxun Li, 2013

机译：具有伴随吲哚支管的铑和铂催化4 + 3环加成：Cyclohepta的合成B吲哚

One pot hydroamination/[4+3] cycloaddition: synthesis towards the cyclohepta[b]indole core of silicine and ervatamine

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