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Copper-catalysed reductive amination of nitriles and organic-group reductions using dimethylamine borane

机译:铜催化的腈还原胺化和使用二甲胺硼烷的有机基还原

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摘要

A heterogeneous copper catalyst, formed in situ, has been shown to dehydrocouple commercially available amine boranes whilst transferring hydrogen for the reduction of selected organic functional groups in an aqueous medium. The catalytic system has also been shown to promote the reductive amination of aryl nitriles.
机译:已显示原位形成的多相铜催化剂可将市售的胺硼烷脱氢偶联,同时转移氢以还原水性介质中的所选有机官能团。还显示出催化体系可促进芳基腈的还原胺化。

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