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Mechanical properties of commercial copper current-collector foils

机译:商业铜集电器箔的机械性能

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The functionality and reliability of the current collector (CC) are crucial to design and fabricate electrodes for Li-ion batteries because the CC serves as the bridge between external electronic and internal Li-ion transports. Therefore, understanding the mechanical behavior of CCs is of great importance for battery design and manufacturing. In this paper, we report the measured values of the elastic moduli of six commercial copper current-collector (CCC) foils. Measurements were performed using three techniques: a standard microtensile testing machine equipped with a laser sensor, dynamic mechanical analysis (DMA), and nanoindentation. For electrolytic copper (E-Cu) foils, we find elastic moduli of approximately 70 GPa, and for rolled copper (R-Cu) foils, we find elastic moduli of approximately 50 GPa. Values for yield strength and fracture strength of the foils were determined from load-deflection curves; the results are consistent with values recommended by the manufacturer. Crystalline structures, which influence values for the elastic moduli of the foils, were investigated by X-ray diffraction. Surface morphologies of the foils before testing and the fracture morphologies after testing were studied by scanning electron microscopy.
机译:集电器(CC)的功能和可靠性对于设计和制造锂离子电池的电极至关重要,因为CC充当外部电子和内部锂离子传输之间的桥梁。因此,了解CC的机械性能对于电池设计和制造非常重要。在本文中,我们报告了六种商用铜集电器(CCC)箔的弹性模量的测量值。使用三种技术进行测量:配备激光传感器的标准微拉伸试验机,动态力学分析(DMA)和纳米压痕。对于电解铜(E-Cu)箔,我们发现约70 GPa的弹性模量,对于压延铜(R-Cu)箔,我们发现约50 GPa的弹性模量。箔片的屈服强度和断裂强度的值由载荷-挠度曲线确定。结果与制造商推荐的值一致。通过X射线衍射研究了影响箔的弹性模量值的晶体结构。通过扫描电子显微镜研究了测试之前的箔的表面形态和测试之后的断裂形态。

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