Nano rutile TiO2 catalysed synthesis of (E)-4-(2-(1-(4-chlorophenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)vinyl)-N,N-dimethylaniline and its interaction with super paramagnetic nanoparticles

Thanikachalam V.; Arunpandiyan A.; Jayabharathi J.; Karunakaran C.; Ramanathan P.

首页> 外文期刊>RSC Advances >Nano rutile TiO2 catalysed synthesis of (E)-4-(2-(1-(4-chlorophenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)vinyl)-N,N-dimethylaniline and its interaction with super paramagnetic nanoparticles

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Nano rutile TiO2 catalysed synthesis of (E)-4-(2-(1-(4-chlorophenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)vinyl)-N,N-dimethylaniline and its interaction with super paramagnetic nanoparticles

机译：纳米金红石型TiO2催化合成（E）-4-（2-（1-（4-（氯氯苯基）-1H-菲并[9,10-d]咪唑-2-基）乙烯基）-N，N-二甲基苯胺与超顺磁性纳米粒子的相互作用

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The synthesis of (E)-4-(2-(1-(4-chlorophenyl)-1H-phenanthro[ 9,10-d]imidazol-2-yl)vinyl)-N,N-dimethylaniline (CPPIVI) has been carried out using TiO2 (R) as catalyst under solvent free conditions and characterized by NMR spectral studies. The catalyst was characterized by scanning electron microscopy (SEM) and Xray diffractometry (XRD). The catalyst is reusable with satisfactory results. The synthesised phosphated styrylimidazole (PSI) and phosphated styrylimidazole bound magnetic nanoparticles (PSIMN) were characterized using SEM, transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), XRD and Fourier-transform infrared spectroscopy (FT-IR). The intensities of the absorption and emission maxima are of the following order: PSIMN > PSI > CPPIVI. Conductance and VSM measurements were also carried out. The lifetime of the excited states of PSIMN, PSI and CPPIVI has been obtained. A prototropic study of CPPIVI has also been made at different concentrations.

机译：（E）-4-（2-（1-（1-（4-氯苯基）-1H-菲[9,10-d]咪唑-2-基）乙烯基）-N，N-二甲基苯胺（CPPIVI）的合成在无溶剂条件下使用TiO2（R）作为催化剂进行反应，并通过NMR光谱研究进行表征。通过扫描电子显微镜（SEM）和X射线衍射仪（XRD）表征催化剂。该催化剂可重复使用，结果令人满意。利用SEM，透射电子显微镜（TEM），能量色散X射线光谱（EDS），XRD和傅里叶变换红外光谱（FT-IR）对合成的磷酸苯乙烯基咪唑（PSI）和磷酸苯乙烯基咪唑结合的磁性纳米粒子（PSIMN）进行了表征。。吸收和发射最大值的强度按以下顺序排列：PSIMN> PSI> CPPIVI。还进行了电导和VSM测量。获得了PSIMN，PSI和CPPIVI激发态的寿命。还对CPPIVI进行了质子学研究，浓度不同。

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《RSC Advances》 |2014年第107期|共9页
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Thanikachalam V.; Arunpandiyan A.; Jayabharathi J.; Karunakaran C.; Ramanathan P.;
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1. Nano rutile TiO2 catalysed synthesis of (E)-4-(2-(1-(4-chlorophenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)vinyl)-N,N-dimethylaniline and its interaction with super paramagnetic nanoparticles [J] . Thanikachalam V., Arunpandiyan A., Jayabharathi J., RSC Advances . 2014,第107期

机译：纳米金红石型TiO2催化合成（E）-4-（2-（1-（4-（氯氯苯基）-1H-菲并[9,10-d]咪唑-2-基）乙烯基）-N，N-二甲基苯胺与超顺磁性纳米粒子的相互作用
2. Synthesis of 5-(4-(1H-phenanthro[9,10-d]imidazol-2-yl)benzylidene) thiazolidine-2,4-dione as promising DNA and serum albumin-binding agents and evaluation of antitumor activity [J] . Singh Iqubal, Rani Richa, Luxami Vijay, European Journal of Medicinal Chemistry: Chimie Therapeutique . 2019,第期

机译：合成5-（4-（1H-（1H-（1H-（1H-菲拉米咪唑-2-基）苄基那）噻唑烷-2,4-二酮作为有前途的DNA和血清白蛋白结合剂和抗肿瘤活性的评价
3. Synthesis, spectroscopic, physicochemical properties and binding site analysis of 4-(1H-phenanthro[9,10-d]-imidazol-2-yl)-benzaldehyde fluorescent probe for imaging in cell biology: Experimental and theoretical study [J] . Krawczyk Przemyslaw, Jedrzejewska Beata, Pietrzak Marek, Journal of Photochemistry and Photobiology, B. Biology: Official Journal of the European Society for Photobiology . 2016,第Null期

机译：用于细胞生物学成像的4-（1H-菲[9,10-d]-咪唑-2-基）-苯甲醛荧光探针的合成，光谱，理化性质和结合位点分析：实验和理论研究
4. Synthesis and characterization of TiO2 nanoparticles: anatase, brookite, and rutile [C] . David Reyes-Coronado, Geonel Rodriguez-Gattorno, Manuel Espinosa-Pesqueira, Conference on Solar Hydrogen and Nanotechnology . 2007

机译：TiO2纳米粒子的合成与表征：锐钛矿，布鲁克钛和金红石
5. Study of paramagnetic defect centers in as-grown and annealed TiO2 anatase and rutile nanoparticles by a variable-temperature X-band and high-frequency (236 GHz) EPR [O] . S.K. Misra, S.I. Andronenko, D. Tipikin, -1

机译：利用可变温度X波段和高频（236 GHz）EPR研究退火后的TiO2锐钛矿和金红石纳米粒子的顺磁缺陷中心
6. 1-(4-Methoxyphenyl)-2-[4-(trifluoromethyl)phenyl]-1H-phenanthro[9,10-d]imidazole [O] . P. Sakthivel, A. Pasupathi, J. Jayabharathi, 2013

机译：1-（4-甲氧基苯基）-2- [4-（三氟甲基）苯基] -1H-菲并[9,10-d]咪唑

Nano rutile TiO2 catalysed synthesis of (E)-4-(2-(1-(4-chlorophenyl)-1H-phenanthro[9,10-d]imidazol-2-yl)vinyl)-N,N-dimethylaniline and its interaction with super paramagnetic nanoparticles

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