Stereoselective synthesis of cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes

N. V. Vorontsova; V. I. Rozenberg; E. V. Vorontsov; D. Yu. Antonov; Z. A. Starikova; Yu. N. Bubnov

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Stereoselective synthesis of cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes

机译：立体选择性合成顺式4,7-二取代的4,7-二羟基-4,7-二氢[2.2]对环环烷

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The nucleophilic addition of butyllithium, phenyllithium, methyllithium, and triallylborane to [2.2]paracyclophane-4,7-quinone (1) proceeded regio- and stereospecifically to give the corresponding cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes 2-5 with the endo orientation of the hydroxy groups. The structures of quinone 1 and diols 2, 4, and 5 were established by X-ray diffraction analysis.

机译：丁基锂，苯基锂，甲基锂和三烯丙基硼烷在[2.2]对环phan-4,7-醌（1）上的亲核加成反应在区域和立体上进行，得到相应的cis-4,7-二取代4,7-dihydroxy-4，具有羟基的内向的7-二氢[2.2]对环环烷2-5。通过X射线衍射分析建立了醌1和二醇2、4和5的结构。

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《Russian Chemical Bulletin》 |2002年第8期|共8页
作者
N. V. Vorontsova; V. I. Rozenberg; E. V. Vorontsov; D. Yu. Antonov; Z. A. Starikova; Yu. N. Bubnov;
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正文语种 eng
中图分类化学;
关键词
2.2paracyclophanes; quinones; nucleophilic addition; organolithium compounds; organoboron compounds; allylboration; stereoselectivity; X-ray diffraction analysis;

机译：[2.2]对环烷;醌;亲核加成;有机锂化合物;有机硼化合物;烯丙基化;立体选择性;X射线衍射分析;

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1. Stereoselective synthesis of cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes [J] . N. V. Vorontsova, V. I. Rozenberg, E. V. Vorontsov, Russian Chemical Bulletin . 2002,第8期

机译：立体选择性合成顺式4,7-二取代的4,7-二羟基-4,7-二氢[2.2]对环环烷
2. Unusual Rearrangements of cis-4,7-Disubstituted 4,7-Dihydro-4,7-dihydroxy[2.2]paracyclophanes on Dehydration: Stereoselective Formation of Planar Chiral Cyclohexadienones [J] . Natalia Vorontsova, Valeria Rozenberg, Evgenii Vorontsov, European journal of organic chemistry . 2003,第4期

机译：脱水时顺式-4,7-二取代的4,7-二氢-4,7-二羟基[2.2]对环环糊精的异常重排：平面手性环己二酮的立体选择性形成
3. Unusual rearrangement upon dehydration of cis-4,7-diallyl-4,7-dihdyroxy-4,7-dihydro[2.2]paracyclophane [J] . N.V.Vorontsova, V.I.Rozenberg, E.V.Vorontsov, Russian Chemical Bulletin . 2000,第6期

机译：顺式-4,7-二烯丙基-4,7-二乙氧基-4,7-二氢[2.2]对环环糊精脱水后异常重排
4. Synthesis and Properties of Novel Through-Space Conjugated Polymer with 2.2Paracyclophane and Ferrocene in the Main Chain [C] . Yasuhiro Morisaki, Yoshiki Chujo Symposium on Organometallic Chemistry . 2003

机译：具有2.2截晶烷和主要链中的新型通过空间缀合聚合物的合成与性能和主链中的二茂铁
5. Synthesis of perfluoro[2.2]paracyclophane and its nucleophilic substitutions [D] . Zhang, Lianhao. 2009

机译：全氟[2.2]对环烷的合成及其亲核取代
6. Synthesis of New Planar-Chiral Linked 2.2Paracyclophanes-N-(2.2-Paracyclophanylcarbamoyl)-4-(2.2Paracyclophanylcarboxamide 2.2Paracyclophanyl-Substituted Triazolthiones and -Substituted Oxadiazoles [O] . Ashraf A. Aly, Stefan Bräse, Alaa A. Hassan, 2020

机译：合成新平面 - 手性连接2.2截谱 - N - （2.2 -Alaryclophanylcarbamoyl）-4 - （2.2截晶蛋白基甲酰胺2.2截晶粒子取代的三唑基和 - 取代的恶唑
7. An Efficient and Straightforward Access to Sulfur Substituted 2.2Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation [O] . -1

机译：对硫的高效和直接进入硫取代2.2截谱蛋白：应用于立体选择性硫酸盐盐烷基化
8. Organotransition-Metal Metallacarboranes. 8. Mono-, Di-, and Triiron Polyarene Sandwich Complexes of Et2C2B4H4(2-) Containing Fluorene, 9,10-Dihydroanthracene, or (2.2)Paracyclophane Ligands [R] . Spencer, J. T., Grimes, R. N. 1987

机译：有机过渡 - 金属金属碳硼烷。 8.含有芴，9,10-二氢蒽或（2.2）对环芳烷配体的Et2C2B4H4（2-）的单 - ，二 - 和三铁聚芳烃夹心复合物

Stereoselective synthesis of cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes

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