首页> 外文期刊>Russian Journal of General Chemistry >Phthalocyanines and Related Compounds:XLV.Nucleophilic Substitution of Chlorine in Tetrachlorophthalonitrile:Synthesis of Aryloxy-Aubstituted Phthalonitriles and Phthalocyanines Derived from Them
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Phthalocyanines and Related Compounds:XLV.Nucleophilic Substitution of Chlorine in Tetrachlorophthalonitrile:Synthesis of Aryloxy-Aubstituted Phthalonitriles and Phthalocyanines Derived from Them

机译:酞菁和相关化合物:XLV。四氯邻苯二甲腈中的氯亲核取代:芳氧基取代的邻苯二甲腈和衍生自它们的邻苯二甲腈的合成

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摘要

Nucleophilic substitution of chlorine in tetrachlorophthalonitrile by the reaction with aryloxy anions is studied.Depending on the reactant ratio,the products of substitution of one,two,and/or three chlorine atoms are formed.Their tetramerization gives aryloxychloro-substituted phthalocyanines having the absorption band in the near-IR range.
机译:研究了四氯邻苯二甲腈与芳氧基阴离子反应进行的亲核取代。根据反应物的比例,形成一个,两个和/或三个氯原子的取代产物。它们的四聚反应得到具有吸收带的芳氧基氯取代的酞菁。在近红外范围内。

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