Unexpected Formation of 1,6-Bis[3,5-dimethyl-4-(1,4,6-oxa-dithiocan-5-yl)-1H-pyrazol-1-yl]hexane in the Reaction of 1,1'-(Hexane-1,6-diyl)bis[3,5-dimethyl-1H-pyrazole-4-carbaldehyde]with 2-Sulfanylethanol

L.K.Papernaya; E.V.Rudyakova; A.I.Albanov

首页> 外文期刊>Russian Journal of Organic Chemistry >Unexpected Formation of 1,6-Bis[3,5-dimethyl-4-(1,4,6-oxa-dithiocan-5-yl)-1H-pyrazol-1-yl]hexane in the Reaction of 1,1'-(Hexane-1,6-diyl)bis[3,5-dimethyl-1H-pyrazole-4-carbaldehyde]with 2-Sulfanylethanol

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Unexpected Formation of 1,6-Bis[3,5-dimethyl-4-(1,4,6-oxa-dithiocan-5-yl)-1H-pyrazol-1-yl]hexane in the Reaction of 1,1'-(Hexane-1,6-diyl)bis[3,5-dimethyl-1H-pyrazole-4-carbaldehyde]with 2-Sulfanylethanol

机译：1,1'反应中意外生成1,6-双[3,5-二甲基-4-（1,4,6-氧杂二硫代-5-基）-1H-吡唑-1-基]己烷-（己烷-1,6-二基）双[3,5-二甲基-1H-吡唑-4-甲醛）与2-硫烷基乙醇

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We previously reported that reactions of aldehydes of the thiophene series[1-3]with alkanethiols and dithiols in the presence of chloro(trimethyl)silane Me3SiCl at reduced temperature provide a simple and convenient synthetic route to acyclic and cyclic dithio-acetals possessing thiophene fragments.It is also known that 2-sulfanylethanol and 3-sulfanylpropan-1-ol react with aliphatic and aromatic aldehydes in the presence of scandium trifluoromethanesulfonate[4],boron trifluoride[5],or p-toluenesulfonic acid[6]to give the corresponding 1,3-oxathiolane and 1,3-oxa-thiane derivatives.

机译：我们以前曾报道过，噻吩系列[1-3]的醛与链烷硫醇和二硫醇在氯（三甲基）硅烷Me3SiCl的存在下，在较低的温度下反应，提供了一种简单且方便的合成路线，以合成具有噻吩片段的无环和环状二硫代缩醛还已知在三氟甲烷磺酸scan [4]，三氟化硼[5]或对甲苯磺酸[6]存在下，2-硫烷基乙醇和3-硫烷基丙烷-1-醇与脂肪族和芳香族醛反应。相应的1,3-氧杂硫杂环戊烷和1,3-氧杂噻吩衍生物。

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《Russian Journal of Organic Chemistry》 |2008年第10期|共2页
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L.K.Papernaya; E.V.Rudyakova; A.I.Albanov;
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1. Unexpected Formation of 1,6-Bis[3,5-dimethyl-4-(1,4,6-oxa-dithiocan-5-yl)-1H-pyrazol-1-yl]hexane in the Reaction of 1,1'-(Hexane-1,6-diyl)bis[3,5-dimethyl-1H-pyrazole-4-carbaldehyde]with 2-Sulfanylethanol [J] . L.K.Papernaya, E.V.Rudyakova, A.I.Albanov Russian Journal of Organic Chemistry . 2008,第10期

机译：1,1'反应中意外生成1,6-双[3,5-二甲基-4-（1,4,6-氧杂二硫代-5-基）-1H-吡唑-1-基]己烷-（己烷-1,6-二基）双[3,5-二甲基-1H-吡唑-4-甲醛）与2-硫烷基乙醇
2. A 26-Membered Macrocycle Obtained by a Double Diels–Alder Cycloaddition Between Two 2H-Pyran-2-one Rings and Two 1,1'-(Hexane-1,6-diyl)bis(1H-pyrrole-2,5-dione)s [J] . Bor Lucijan Turek, Marijan Ko?evar, Kri?tof Kranjc, Acta Chimica Slovenica . 2017,第4期

机译：通过两种二氧化物-2-一个环和两个1,1'（己烷-1,6-二基）双（1H-吡咯-2,5-二酮）之间的双Diels-alder环加成而获得的26元宏循环。（1H-吡咯-2,5-二酮））S.
3. A 26-Membered Macrocycle Obtained by a Double Diels-Alder Cycloaddition Between Two 2H-Pyran-2-one Rings and Two 1,1 '-(Hexane-1,6-diyl)bis (1H-pyrrole-2,5-dione)s [J] . Turek Bor Lucijan, Kocevar Marijan, Kranjc Kristof, Acta Chimica Slovenica . 2017,第4期

机译：通过两种二氧化物-2-一环和两个1,1'（己烷-1,6-二基）双（1H-吡咯-2,5-二酮）之间的双丁 - 桤木环加成而获得的26元宏环。（1H-吡咯-2,5-二酮）S.
4. Synthesis, characterization and luminescence of europium, terbium complexes of 1,1'-(pyridin-2,6-diyl)bis-3-p-tolylpropane-1,3-dione [C] . Jinliang Zhu, Shengli Liu, Liangcai Yu, International conference on advanced materials . 2011

机译：合成，表征和发光的铕，铽络合物1,1' - （吡啶-2,6-二基）双-3-甲苯基丙烷-1,3-二酮
5. THE FORMATION OF 1-METHYL-6,7-BENZOBICYCLO(3.2.2)NON-6-ENE FROM THE FRIEDEL-CRAFTS REACTION OF 1,1-BIS(BROMOMETHYL)CYCLOHEXANE WITH BENZENE. [D] . FUCHS, PAUL IRVING. 1976

机译：1，1-双（溴甲基）环己烷与苯的弗里德尔-克拉夫茨反应形成的1-甲基-6,7-苯并双环（3.2.2）非-6-烯。
6. Poly[di-μ-cis-cyclohexane-1,4-dicarboxylato-μ-trans-cyclohexane-1,4-dicarboxylato-bis[dipyrido[3,2-a:2′,3′-c]phenazine]trimanganese(II)] [O] . Wen-Zhi Zhang, Xiao-Huan Yuan 2015

机译：聚[di-μ-顺式环己烷-1,4-二羧酸酯-μ-反式环己烷-1,4-二羧酸酯-双[dipyrido [3,2-a：2'，3'-c]吩嗪]三苯甲基（ II）]
7. 1,1′-{(Hexane-1,6-diyl)bis[(azaniumylylidene)methanylylidene]}bis(naphthalen-2-olate) [O] . Kamel Ouari, Sabrina Bendia, Moufida Merzougui, 2015

机译：1,1' - {（己烷-1,6-二基）双[（azaniumylylidene）methanylylidene]}双（萘-2-醇盐）
8. Preliminary Information from an Ongoing Combined Repeated Dose Toxicity Study with a Reproductive/Developmental Toxicity Screening Test in Rats and a Final Report of a 28-Day Repeated-Dose Study in Rats with 1,6bis(trimethoxysilyl)hexane. [R] . 2009

机译：来自正在进行的联合重复剂量毒性研究与大鼠的生殖/发育毒性筛选试验的初步信息以及在具有1,6bis（三甲氧基甲硅烷基）己烷的大鼠中的28天重复剂量研究的最终报告。

Unexpected Formation of 1,6-Bis[3,5-dimethyl-4-(1,4,6-oxa-dithiocan-5-yl)-1H-pyrazol-1-yl]hexane in the Reaction of 1,1'-(Hexane-1,6-diyl)bis[3,5-dimethyl-1H-pyrazole-4-carbaldehyde]with 2-Sulfanylethanol

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