Chemical transformations of CO_2 in trifluoroacetic acid solutions

Vishnetskaya M.V.; Ivanova M.S.; Svichkarev O.M.; Budynina E.M.; MelNikov M.Ya.

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Chemical transformations of CO_2 in trifluoroacetic acid solutions

机译：三氟乙酸溶液中CO_2的化学转化

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摘要

It is established that a conversion reaction of carbon dioxide takes place at room temperature and atmospheric pressure in aqueous solutions of trifluoroacetic acid (TFA), which leads to the formation of oxalic acid and heavier polymerized products.

机译：已经确定，二氧化碳的转化反应在室温和大气压下在三氟乙酸（TFA）的水溶液中发生，这导致草酸的形成和更重的聚合产物。

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来源
《Russian Journal of Physical Chemistry》 |2013年第5期|共3页
作者
Vishnetskaya M.V.; Ivanova M.S.; Svichkarev O.M.; Budynina E.M.; MelNikov M.Ya.;
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原文格式 PDF
正文语种 eng
中图分类 54.2;
关键词
activation; C-C bond; carbon dioxide; molecular oxygen; trifluoroacetic acid solutions;

机译：活化;C-C键;二氧化碳;分子氧;三氟乙酸溶液;

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1. Chemical transformations of CO_2 in trifluoroacetic acid solutions [J] . Vishnetskaya M.V., Ivanova M.S., Svichkarev O.M., Russian Journal of Physical Chemistry . 2013,第5期

机译：三氟乙酸溶液中CO_2的化学转化
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3. Effect electrochemical conversion of CO_2 to CO, C_2H_4 and CH_4 at a three-phase interface on a Cu net electrode in acidic solution [J] . H. Yano, F. Shirai, M. Nakayama, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2002,第1a2期

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4. Oscillatory Phenomena During Anodic Copper Electrodissolution in Trifluoroacetic Acid Solution [C] . N. Potkonjak, Lj. Kolar-Anic, T. Potkonjak, Yugoslav Materials Research Society Conference . 2006

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6. Electrophilic mercuration and thallation of benzene and substituted benzenes in trifluoroacetic acid solution [O] . George A. Olah, Iwao Hashimoto, Henry C. Lin 1977

机译：三氟乙酸溶液中苯和取代苯的亲电性巯基化和巯基化
7. Organic reactions for the electrochemical and photochemical production of chemical fuels from CO_2 – The reduction chemistry of carboxylic acids and derivatives as bent CO_2 surrogates [O] . Luca Oana R., Fenwick Aidan Q. 2015

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8. Trifluoroacetic Acid: Accumulation from Aqueous Solution by the Roots of Sunflower (helianthus Annuus), with Cover Letter dated 10/28/94. [R] . 1994

机译：三氟乙酸：向日葵根（Helianthus annuus）从水溶液中积累，封面信日期为10/28/94。

Chemical transformations of CO_2 in trifluoroacetic acid solutions

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