Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides

Gnanamgari D; Crabtree RH

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Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides

机译：特吡啶吡啶钌催化的一氧化碳将醛转化为酰胺

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摘要

TerpyRu(PPh3)Cl-2 is an efficient catalyst for rearranging aldoximes to amides without the need for chelating phosphines or additives as in prior examples. The catalyst is also useful in converting aldehydes into amides in a one-pot process using NaHCO3 as an additive. A mechanism involving nucleophilic attack of deprotonated oxime on an adjacent nitrile is suggested.

机译：TerpyRu（PPh3）Cl-2是一种有效的催化剂，可将醛肟重排为酰胺，而无需像先前的实施例那样螯合膦或添加剂。该催化剂还可用于使用NaHCO3作为添加剂的一锅法将醛转化为酰胺的过程。建议了一种机制，涉及去质子化肟对相邻腈的亲核攻击。

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《Organometallics》 |2009年第3期|共3页
作者
Gnanamgari D; Crabtree RH;
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正文语种 eng
中图分类有机化学;
关键词
HIGHLY EFFICIENT; OXO COMPLEXES; ALDOXIMES; ALCOHOLS; OXIDATION; NITRILES; TRANSFORMATION; HYDROGEN; LIGANDS; CYCLOPROPANATION;

机译：高效;含氧化合物;醛肟;醇;氧化;腈;转化;氢;液体;环丙烷化;

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1. Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides [J] . Gnanamgari D, Crabtree RH Organometallics . 2009,第3期

机译：特吡啶吡啶钌催化的一氧化碳将醛转化为酰胺
2. A facile, one-pot procedure for the conversion of aromatic aldehydes to esters, as well as thioesters and amides, via acyl hydrazide intermediates [J] . Maruani Antoine, Lee Maximillian T. W., Watkins George, RSC Advances . 2016,第4期

机译：通过酰基酰肼中间体将芳香醛转化为酯，以及硫代酰酯和酰胺的容易的单罐方法
3. Synthesis of Ru(II) pyridoxal thiosemicarbazone complex and its catalytic application to one-pot conversion of aldehydes to primary amides [J] . Kanchanadevi Appukutti, Ramesh Rengan, Semeril David Inorganic Chemistry Communications . 2015,第Null期

机译：Ru（II）吡ido醛硫半碳杂zone配合物的合成及其在醛一锅转化为伯酰胺中的催化应用
4. Ruthenium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes [C] . Fumitoshi Shibahara, John F. Bower, Michael J. Krische Symposium on Organometallic Chemistry . 2008

机译：来自醇或醛氧化水平的钌催化的羰基烯丙基，采用无环1,3-二烯
5. I. Solvent-free oxidation of primary ARYL alcohols to aldehydes, and, II. Conversion of primary amide to nitrile using silicon tetrachloride as the dehydrating agent. [D] . Pedraza, Fernando. 2006

机译：I.芳族伯醇无溶剂氧化为醛，以及II。使用四氯化硅作为脱水剂将伯酰胺转化为腈。
6. A Simple One-pot Conversion of Aldehydes and Ketones to Enals [O] . Petr Valenta, Natalie A. Drucker, Jeffrey W. Bode, -1

机译：醛的一个简单的一锅转变和酮与Enals
7. A facile, one-pot procedure for the conversion of aromatic aldehydes to esters, as well as thioesters and amides, via acyl hydrazide intermediates [O] . Antoine Maruani, Maximillian T. W. Lee, George Watkins, 2016

机译：通过酰基酰肼中间体将芳香醛转化为酯，以及硫代酰酯和酰胺的容易的单罐方法

Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides

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