Reaction of Iodoform and Isopropyl Grignard Reagent Revisited

Reinhard W.Hoffmann; Michael Muller; Karsten Menzel; Ruth Gschwind; Peter Schwerdtfeger; Olga L.Malkina; Vladimir G.Malkin

首页> 外文期刊>Organometallics >Reaction of Iodoform and Isopropyl Grignard Reagent Revisited

【24h】

Reaction of Iodoform and Isopropyl Grignard Reagent Revisited

机译：再谈碘仿和异丙格氏试剂的反应

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new long-lived intermediate has been identified in the reaction of iodoform (1) with isopropylmagnesium chloride at -78 deg C. The structure of the symmetrical iodine ate complex 7, I_2CH-I-CHI_2-MgCl~+, has been assigned to the deep red intermediate by NMR spectroscopic techniques, supported by calculation of ~1J_(C-H), ~2J_(C-C), and ~3J_(C-H) coupling constants.

机译：在-78℃下，碘仿（1）与异丙基氯化镁的反应中已鉴定出一种新的长寿命中间体。对称碘酸盐络合物7 I_2CH-I-CHI_2-MgCl〜+的结构已确定为NMR光谱技术测定深红色中间体，并通过计算〜1J_（CH），〜2J_（CC）和〜3J_（CH）耦合常数来支持。

著录项

来源
《Organometallics》 |2001年第25期|共4页
作者
Reinhard W.Hoffmann; Michael Muller; Karsten Menzel; Ruth Gschwind; Peter Schwerdtfeger; Olga L.Malkina; Vladimir G.Malkin;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;有机质材料;
关键词

相似文献

外文文献
中文文献
专利

1. Reaction of Iodoform and Isopropyl Grignard Reagent Revisited [J] . Reinhard W.Hoffmann, Michael Muller, Karsten Menzel, Organometallics . 2001,第25期

机译：再谈碘仿和异丙格氏试剂的反应
2. The retro Grignard addition reaction revisited: the reversible addition of benzyl reagents to ketones [J] . Stig Holden Christensen, Torkil Holm, Robert Madsen Tetrahedron . 2014,第7期

机译：重新进行了格利雅（Grignard）复古加成反应：将苄基试剂可逆地添加到酮中
3. The grignard reaction of cyclodextrin-6-aldehydes revisited: A study of the stereoselectivity upon addition of organometallic reagents to aldehydes and ketones [J] . Lindb?ck E., Zhou Y., Marinescu L., European journal of organic chemistry . 2010,第20期

机译：环糊精6醛的格利雅反应再谈：在醛和酮中添加有机金属试剂后的立体选择性研究
4. DEVELOPMENT OF NOVEL PHOSPHONIUM IONIC LIQUID FOR GRIGNARD REACTION: IRON SALT-CATALYZED RAPID HOMOCOUPLING REACTION OF ARYL GRIGNARD REAGENTS [C] . Toshiyuki Itoh, Keisuke Kude, Akihiko Ishioka, Organic and Biology Electrochemistry Symposium in Honor of Yoshihiro Matsumura . 2008

机译：RIG反应的新型磷离子液体的开发：铁盐催化的芳基G试剂的快速同质反应
5. Mechanistic and Stereochemical Insights into the Reactions of Allylic Grignard Reagents with Carbonyl Compounds [D] . Bartolo, Nicole. 2021

机译：用羰基化合物的烯丙基格子试剂反应的机械和立体化学见解
6. Two Palladium-Catalyzed Domino Reactions from One Set of Substrates/Reagents: Efficient Synthesis of Substituted Indenes and cis-Stilbenoid Hydrocarbons from the Same Internal Alkynes and Hindered Grignard Reagents [O] . Cheng-Guo Dong, Pik Yeung, Qiao-Sheng Hu -1

机译：从一组底物/试剂中进行两个钯催化的多米诺反应：从相同的内部炔烃和受阻的格氏试剂中高效合成取代的茚类和顺式-类苯乙烯烃
7. The retro Grignard addition reaction revisited: the reversible addition of benzyl reagents to ketones [O] . Christensen Stig Holden, Holm Torkil, Madsen Robert 2014

机译：重新审视了复古的格氏加成反应：将苄基试剂可逆地添加到酮中
8. Solvation of Pseudo – Grignard Reagents and The Kinetics of Pseudo - Grignard Reactions [R] . H. A. Wolterman 1972

机译：伪格氏试剂的溶剂化和伪格氏反应动力学

Reaction of Iodoform and Isopropyl Grignard Reagent Revisited

摘要

著录项

相似文献

相关主题

期刊订阅