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Hollow fiber supported liquid membrane for extraction of ethylbenzene and nitrobenzene from aqueous solution: A Hansen Solubility Parameter approach

机译:中空纤维负载液膜从水溶液中萃取乙苯和硝基苯的汉森溶解度参数法

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摘要

A hollow fiber supported liquid membrane (HFSLM) method was developed to extract organic pollutants (ethylbenzene and nitrobenzene) from aqueous solution, which provided a high selectivity and extraction efficiency. It was a two-phase system. The microporous hydrophobic polyethersulfone (PES) hollow fiber membrane which was made in our laboratory was used as the solid support for the liquid membrane, n-undecane, n-dodecane, n-heptanol and n-octanol were used as organic extractants which were located inside the pores and the lumens of the hollow fibers. The organic pollutants were extracted from aqueous phase into organic phase. A new approach of choosing the organic extractants which was based on Hansen Solubility Parameters (HSP) theory was proposed. The selectivity and extraction performance of organic extractants to ethylbenzene and nitrobenzene were successfully related to HSP values. The effect of different parameters such as operation temperature, flow rates of aqueous phase and organic phase, initial concentration of organic pollutants and pH value in aqueous phase was also studied.
机译:提出了一种中空纤维支撑液膜(HFSLM)法从水溶液中萃取有机污染物(乙苯和硝基苯),具有较高的选择性和萃取效率。这是一个两阶段系统。我们实验室制得的微孔疏水性聚醚砜(PES)中空纤维膜用作液膜的固体载体,正十一烷,正十二烷,正庚醇和正辛醇用作有机萃取剂,位于在中空纤维的孔和内腔中。将有机污染物从水相萃取到有机相中。提出了一种基于Hansen溶解度参数(HSP)理论的有机萃取剂选择新方法。有机萃取剂对乙苯和硝基苯的选择性和萃取性能与HSP值成功相关。还研究了操作温度,水相和有机相的流速,有机污染物的初始浓度和水相pH值等不同参数的影响。

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