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Removal of nonsteroidal anti-inflammatory drugs (NSAIDs) by electrocoagulation-flotation with a cationic surfactant

机译:通过阳离子表面活性剂的电凝浮选去除非甾体类抗炎药(NSAIDs)

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An electrocoagulation flotation (ECF) process was used to remove selected nonsteroidal anti-inflammatory drugs (NSAIDs), specifically diclofenac, ibuprofen, and ketoprofen, from water. A cationic surfactant, cethyltrimethyl ammonium bromide (CTAB), was added to the solution as a collector and frother. Without the addition of the cationic surfactant, the removal of NSAIDs in a single-NSAID solution was in the range of 10-45%; it decreased to approximately 10% in multiple-NSAID systems. However, after adding a stoichiometric amount of CTAB, the removal of NSAIDs significantly improved in single-NSAID systems. For multiple-NSAID removal, the concentration of CTAB required to achieve ideal removal was equal to the sum of the molar concentrations of all the NSAIDs. In addition, a high current density produced smaller bubbles, thus enhanced the electro-flotation and achieved better removal performance. Removal of multiple-NSAIDs in actual hospital wastewater was significantly lower due to interference by oils and other hydrophobic substances. (C) 2015 Published by Elsevier B.V.
机译:电凝浮选(ECF)工艺用于从水中去除选定的非甾体抗炎药(NSAID),特别是双氯芬酸,布洛芬和酮洛芬。将阳离子表面活性剂溴化乙基三甲基铵(CTAB)作为收集剂和起泡剂添加到溶液中。在不添加阳离子表面活性剂的情况下,单一NSAID溶液中NSAID的去除率为10-45%;在多个NSAID系统中,它减少到大约10%。但是,在添加化学计量的CTAB之后,单NSAID系统中NSAID的去除明显改善。对于多次NSAID去除,实现理想去除所需的CTAB浓度等于所有NSAID的摩尔浓度之和。另外,高电流密度产生较小的气泡,从而增强了电浮选并实现了更好的去除性能。由于油类和其他疏水性物质的干扰,实际医院废水中多种非甾体抗炎药的去除率明显降低。 (C)2015由Elsevier B.V.发布

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