ESR and electrochemical studies of 2-acylpyridines and 6,6 '-diacyl-2,2 '-bipyridines

Olea-Azar C; Abarca B; Norambuena E; Opazo L; Rigol C; Ballesteros R; Chadlaoui M

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ESR and electrochemical studies of 2-acylpyridines and 6,6 '-diacyl-2,2 '-bipyridines

机译：2-酰基吡啶和6,6'-二酰基-2,2'-联吡啶的ESR和电化学研究

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The ESR spectra of radicals obtained by electrolytic reduction of 2-acylpyridines and 6,6'-diacyl-2,2'-bipyridines were measured in dimethylsulfoxide (DMSO) and analyzed by quantum chemical calculations. The electrochemistry of these compounds was characterized using cyclic voltammetry, in DMSO solvent. The results showed a two step reduction mechanism, first wave was assigned to the generation of the correspondent free radical species, and the second wave was assigned to the dianion derivatives. AM1 and DFT calculations were performed to obtain the optimized geometries, theoretical hyperfine constants, and spin distributions, respectively. The theoretical results are in complete agreement with the experimental ones. (c) 2004 Elsevier B.V. All rights reserved.

机译：在二甲基亚砜（DMSO）中测量通过2-酰基吡啶和6,6'-二酰基-2,2'-联吡啶的电解还原获得的自由基的ESR光谱，并通过量子化学计算进行分析。这些化合物的电化学在DMSO溶剂中使用循环伏安法进行了表征。结果显示出两步还原机理，第一波分配给相应的自由基种类，第二波分配给二价阴离子衍生物。进行AM1和DFT计算分别获得优化的几何形状，理论超精细常数和自旋分布。理论结果与实验结果完全吻合。（c）2004 Elsevier B.V.保留所有权利。

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《Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy》 |2005年第9期|共6页
作者
Olea-Azar C; Abarca B; Norambuena E; Opazo L; Rigol C; Ballesteros R; Chadlaoui M;
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正文语种 eng
中图分类分析化学;
关键词
2-acylpyridines; 6; 6 '-diacyl-2; 2 '-bipyridines; ESR; cyclic voltammetry; DFT; ELECTRON-SPIN RESONANCE; DI-2-PYRIDYL KETONE; REDUCTION; RADICALS; POLAROGRAPHY; ROUTE; SALTS; DISK;

机译：2-酰基吡啶;6;6'-二酰基-2;2'-联吡啶;ESR;循环伏安法;DFT;电子自旋共振;DI-2-吡啶酮;还原;自由基;自由基学;路线图;盐;盐;磁盘;

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1. ESR and electrochemical studies of 2-acylpyridines and 6,6 '-diacyl-2,2 '-bipyridines [J] . Olea-Azar C, Abarca B, Norambuena E, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2005,第9期

机译：2-酰基吡啶和6,6'-二酰基-2,2'-联吡啶的ESR和电化学研究
2. Photoacoustic calorimetry study of ligand photorelease from the Ru(II)bis(2,2 '-bipyridine)(6,6 '-dimethyl-2,2 '-bipyridine) complex in aqueous solution [J] . Word Tarah A., Whittington Christi L., Karolak Aleksandra, Chemical Physics Letters . 2015,第Null期

机译：钌（II）双（2,2'-联吡啶）（6,6'-二甲基-2,2'-联吡啶）络合物中配体光释放的光声量热研究
3. Halogen exchange and scrambling between C-X and M-X ' bonds in copper, nickel, and cobalt complexes of 6,6 '-bis(bromo/chloromethyl)-2,2 '-bipyridine. Structural, electrochemical, and photochemical studies [J] . Ghosh M, Biswas P, Florke U, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第1期

机译：6,6'-双（溴/氯甲基）-2,2'-联吡啶的铜，镍和钴络合物中C-X和M-X'键之间的卤素交换和加扰。结构，电化学和光化学研究
4. Electrochemical behavior of 6,6'-bis(2-hydroxyphenyl)-2,2'-bipyridine and its complexes with nickel(II) and cobalt(II) [C] . Danielle M. Goken, Dennis G. Peters International Symposium on Reactive Intermediates in Organic and Biological Electrochemistry . 2001

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5. Spectroscopic and Electrochemical Studies of [Ru(1,10-phenanthroline) 2(4,4'- dihydroxy-2,2'-bipyridine)]2+ and Related Complexes. [D] . Kuhn, Ashley E. 2017

机译：[Ru（1,10-phenothroline）2（4,4'-dihydroxy-2,2'-bipyridine）] 2+及其相关配合物的光谱和电化学研究。
6. Aqua{6,6-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}copper(II) acetonitrile solvate [O] . Xinfang Wang 2016

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ESR and electrochemical studies of 2-acylpyridines and 6,6 '-diacyl-2,2 '-bipyridines

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