4-Substituted ortho-(Sirylated phenyl) sydnones via a Lithiation-Induced Silicon Migration and Subsequent Reaction with Electrophiles

Kenneth Turnbull; Imad F.Nashashibi

首页> 外文期刊>Synthetic Communications >4-Substituted ortho-(Sirylated phenyl) sydnones via a Lithiation-Induced Silicon Migration and Subsequent Reaction with Electrophiles

【24h】

4-Substituted ortho-(Sirylated phenyl) sydnones via a Lithiation-Induced Silicon Migration and Subsequent Reaction with Electrophiles

机译：通过取代作用诱导的硅迁移并随后与亲电试剂反应，将4-取代的邻-（甲硅烷基化的苯基）sydnones

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Treatment of 3-(2-bromophenyl)-4-silylsydnones 1 with n-butyllithium effects rearrangement to the corresponding ortho-silylphenylsydnone anions 2,which can be trapped with electrophiles to afford 4-substituted ortho-silylphenylsydnones 4a-h in 41-89% yield.

机译：用正丁基锂处理3-（2-溴苯基）-4-甲硅烷基酮1可以重排成相应的邻甲硅烷基苯基丁酮阴离子2，可以用亲电子试剂捕获阴离子，从而在41-89中得到4-取代的邻甲硅烷基苯基丁酮4a-h ％让。

著录项

来源
《Synthetic Communications》 |2007年第6期|共5页
作者
Kenneth Turnbull; Imad F.Nashashibi;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Lithiation; silyl rearrangement; sydnones;

机译：锂化;硅基重排;sydnones;

相似文献

外文文献
中文文献
专利

1. 4-Substituted ortho-(Sirylated phenyl) sydnones via a Lithiation-Induced Silicon Migration and Subsequent Reaction with Electrophiles [J] . Kenneth Turnbull, Imad F.Nashashibi Synthetic Communications . 2007,第4a6期

机译：通过取代作用诱导的硅迁移并随后与亲电试剂反应，将4-取代的邻-（甲硅烷基化的苯基）sydnones
2. GREEN SYNTHESIS OF 4-ACETYL-3-(4-SUBSTITUTED) PHENYL SYDNONES UNDER MICROWAVE IRRADIATION [J] . K.P.Srivastava, P.K.Mishra1 Rasayan Journal of Chemistry . 2009,第1期

机译：微波辐射下绿色合成4-乙酰基-3-（4-取代）苯甲酮
3. Sodium Enolate Derived Reactions of N-Boc and N-benzyl-2-(S)-Pyroglutamates with Electrophiles: Synthesis of 4-Substituted and 2-Substituted Pyroglutamates [J] . Jagdish Prasad, Pradeep K. Golay, Sharad K. Panday Current bioactive compounds . 2018,第3期

机译：N-BOC和N-苄基-2-（S） - 用电子蛋白的吡酰胺衍生的衍生反应：合成4-取代和2取代的吡酰磺酸盐
4. Preparation of Monoethanolamine and 5-Phenyl-2,2'-bipyridine Derivatives and Their Subsequent Tosylation Reactions [C] . Dmitry S. Kopchuk, Igor S. Kovalev, Sougata Santra, International Conference on Modern Synthetic Methodologies for Creating Drugs and Functional Materials . 2019

机译：单乙醇胺和5-苯基-2,2'-硼啶衍生物的制备及其随后的托苯基化反应
5. A STUDY OF THE HYDROLYSIS REACTIONS OF PHENYL SILICON-TRICHLORIDE AND DIMETHYL SILICON-DICHLORIDE IN A LAMINAR FLOW TUBULAR REACTOR. [D] . CAMERON, JOHN HOWARD. 1975

机译：层流管式反应器中苯酚-硅-三甲苯酚和二甲基硅-二氯甲酸酯的水解反应研究。
6. Reassignment of the Structures of Products Produced by Reactions of the Product Believed To Be 2-(1-Phenyl-2-Thiocyanatoethylidene)-malononitrile with Electrophiles [O] . Saleh Mohammed Al-Mousawi, Moustafa Sherief Moustafa, Mohamed Hilmy Elnagdi 2011

机译：由认为是2-（1-苯基-2-硫代氰基亚乙基）-丙二腈与亲电试剂反应产生的产物结构的重新分配
7. Reaction of metallated tert-butyl(phenyl)phosphane oxide with electrophiles as a route to functionalized tertiary phosphane oxides : Alkylation reactions [O] . Haynes RK, Au Yeung TL, Chan WK, 2000

机译：金属化叔丁基（苯基）膦氧化物与亲电试剂的反应，作为官能化叔膦氧化物的途径：烷基化反应

4-Substituted ortho-(Sirylated phenyl) sydnones via a Lithiation-Induced Silicon Migration and Subsequent Reaction with Electrophiles

摘要

著录项

相似文献

相关主题

期刊订阅