New Application of Bromotrimethylsilane:Elaboration of Aldehydes/Ketones into Homologous alpha,beta-Unsaturated Esters via beta-Hydroxy Esters

Suresh C.Suri; Jacob C.Marcischak

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New Application of Bromotrimethylsilane:Elaboration of Aldehydes/Ketones into Homologous alpha,beta-Unsaturated Esters via beta-Hydroxy Esters

机译：溴三甲基硅烷的新应用：通过β-羟基酯将醛/酮加工成同源的α，β-不饱和酯

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摘要

alpha,beta-Unsaturated esters are formed when beta-hydroxy esters react with bromotrimethylsilane which is generated from chlorotrimethylsilane-lithium bromide in acetonitrile.The alpha,beta-unsaturated ester is one of the important chemical functionalities that are encountered very commonly in organic synthesis.

机译：当β-羟基酯与由乙腈中的氯三甲基硅烷-溴化锂生成的溴代三甲基硅烷反应时，会形成α，β-不饱和酯.α，β-不饱和酯是有机合成中非常常见的重要化学官能团之一。

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《Synthetic Communications》 |2005年第3期|共9页
作者
Suresh C.Suri; Jacob C.Marcischak;
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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
Bromotrimethylsilane; beta-hydroxy ester; reformatsky reaction; alpha; beta-unsaturated ester; beta; gamma-unsaturated ester;

机译：溴三甲基硅烷;β-羟基酯;reformatsky反应;α;β-不饱和酯;β;γ-不饱和酯;

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专利

1. New Application of Bromotrimethylsilane:Elaboration of Aldehydes/Ketones into Homologous alpha,beta-Unsaturated Esters via beta-Hydroxy Esters [J] . Suresh C.Suri, Jacob C.Marcischak Synthetic Communications . 2005,第3期

机译：溴三甲基硅烷的新应用：通过β-羟基酯将醛/酮加工成同源的α，β-不饱和酯
2. A one-pot combination of amine and heterocyclic carbine catalysis:direct asymmetric synthesis of beta-hydroxy and beta-malonate esters from alpha,beta-unsaturated aldehydes [J] . Gui-Ling Zhao, Armando Cordova Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第34期

机译：一锅法胺和杂环卡宾催化的组合：由α，β-不饱和醛直接不对称合成β-羟基和β-丙二酸酯
3. DICARBONYLMOLYBDENUM AND TUNGSTEN COMPLEXES OF ALPHA,BETA-UNSATURATED ESTERS - PREPARATION, PROPERTIES AND APPLICATION IN THE COMPLEXATION OF ALPHA,BETA-UNSATURATED KETONES [J] . Schmidt T. Journal of Organometallic Chemistry . 1996,第1a2期

机译：α-贝塔不饱和酮的双羰基钼和钨配合物-α-贝塔不饱和酮的制备，性能和应用
4. 1,4-Addition of Arylboronic Acids to p-Aryl-alpha,beta-unsaturated Ketones and Esters Catalyzed by a Rhodium(I)-chiraphos Complex [C] . Takashi Nishikata, Tetsuji Iyama, Hiroto Tachikawa Symposium on Organometallic Chemistry . 2006

机译：1,4-加入芳基硼酸至p-芳基-α，β-不饱和酮和由铑（I）催化的酯 - 富铬络合物
5. The epoxidation of dienes, alpha,beta-unsaturated ketones, alpha,beta-unsaturated esters and vinyl esters by dimethyldioxirane. [D] . Chen, Hsinhung. 2001

机译：二烯，α，β-不饱和酮，α，β-不饱和酯和乙烯基酯被二甲基二环氧乙烷环氧化。
6. Cytotoxicity and Pro-inflammatory Properties of Aliphatic Alpha Beta-unsaturated Acid and Ester Monomers in RAW264.7 Cells and Their Chemical Reactivity [O] . YUKIO MURAKAMI, AKIFUMI KAWATA, SEIJI SUZUKI, 2019

机译：脂族αβ-不饱和酸和酯单体在RAW264.7细胞中的细胞毒性和促炎特性及其化学反应性
7. Stereoretentive Addition of N-tert-Butylsulfonyl-alpha-Amido Silanes to Aldehydes, Ketones, alpha,beta-Unsaturated Esters, and Imines [O] . Mita, Tsuyoshi, Saito, Keisuke, Sugawara, Masumi, 2016

机译：N-叔丁基磺酰基-α-氨基硅烷与醛，酮，α，β-不饱和酯和亚胺的立体定向加成
8. New Application of Bromotrimethylsilane: Elaboration of Aldehydes/ Ketones into Homologous Alpha-Beta-Unsaturated Esters via Beta-Hydroxy Esters [R] . Suri, S. C. , Marcischak, J. C. 2003

机译：Bromotrimethylsilane的新应用：通过β-羟基酯将醛/酮配制成同系的α-β-不饱和酯

New Application of Bromotrimethylsilane:Elaboration of Aldehydes/Ketones into Homologous alpha,beta-Unsaturated Esters via beta-Hydroxy Esters

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