SYNTHESIS OF BICYCLO[3.2.1]-OCTANONE DERIVATIVES BY METAL CATALYZED DECOMPOSITION OF ALPHA-DIAZOMETHYLKETONES

Banik BK.

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SYNTHESIS OF BICYCLO[3.2.1]-OCTANONE DERIVATIVES BY METAL CATALYZED DECOMPOSITION OF ALPHA-DIAZOMETHYLKETONES

机译：金属催化分解二重氮酮合成双环[3.2.1]-辛酮衍生物

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Highly functionalized bicyclo[3.2.1]-octanone derivatives have been prepared by metal catalyzed decompostion of diazoketones through a net retention of configuration af the benzylic center. [References: 36]

机译：高度官能化的双环[3.2.1]-辛酮衍生物是通过金属催化的苄基中心的净保留，通过重氮酮的金属分解而制备的。 [参考：36]

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《Synthetic Communications》 |1997年第20期|共19页
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Banik BK.;
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正文语种 eng
中图分类有机化学;
关键词
Stereoselective synthesis; Aromatic substituents; Complex diterpenoids; Highly efficient; Facile synthesis; Stereochemistry; Products; Acids; Degradation; Insertion;

机译：立体选择性合成;芳香取代基;复杂的二萜;高效;简便的合成;立体化学;产物;酸;降解;插入;

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1. SYNTHESIS OF BICYCLO[3.2.1]-OCTANONE DERIVATIVES BY METAL CATALYZED DECOMPOSITION OF ALPHA-DIAZOMETHYLKETONES [J] . Banik BK. Synthetic Communications . 1997,第20期

机译：金属催化分解二重氮酮合成双环[3.2.1]-辛酮衍生物
2. Synthesis of bicyclo[3.2.1]octanones via ketyl radical promoted rearrangements under reductive PET conditions [J] . Somnath Yadav, Srirupa Banerjee, Dwijendralal Maji, Tetrahedron . 2007,第45期

机译：还原性PET条件下通过酮基自由基重排合成双环[3.2.1]辛酮
3. Domino Michael-aldol annulations for the stereocontrolled synthesis of bicyclo[3.3.1]nonane and bicyclo[3.2.1]octane derivatives [J] . Promontorio Rossella, Richard Jean-Alexandre, Marson Charles M. RSC Advances . 2016,第115期

机译：Domino Michael-aldol用于立体控制合成的双环[3.3.1]壬烷和双环[3.2.1]辛烷衍生物
4. Large-Scale Synthesis of Thienobenzazepine Derivatives Using Two Efficient Metal Catalyzed Processes Telescoped: Nitro Reduction and Intramolecular Aminocarbonylation [C] . William G. Holloway, Kumiko Takeuchi, Michael L. Prunier, Conference on the Catalysis of Organic Reactions . 2009

机译：使用两种有效的金属催化工艺进行大规模合成Thienobzine衍生物：硝基还原和分子内氨基羰基化
5. Part I: Total Synthesis of (+/-)-Pallambins C and D, and, Part II: Gold-Catalyzed Tandem Cyclization towards Substituted Bicyclo[3.2.1]Octenone Derivatives: Lead to Total Synthesis of Dhilirolides A-D. [D] . Xu, Xuesong. 2013

机译：第一部分：（+/-）-戊二烯C和D的全合成，第二部分：金催化的串联环化反应取代双环[3.2.1]大黄酮衍生物：导致Dhilirolides A-D的全合成。
6. Transition-Metal-Catalyzed Diarylation of Isocyanides with Triarylbismuthines for the Selective Synthesis of Imine Derivatives [O] . Shintaro Kodama, Yuki Yamamoto, Yohsuke Kobiki, 2021

机译：具有三芳基铋的异氰酸酯的过渡金属催化的二氰化物用于选择性合成亚胺衍生物
7. Domino Michael-aldol annulations for the stereocontrolled synthesis of bicyclo3.3.1nonane and bicyclo3.2.1octane derivatives [O] . Rossella Promontorio, Jean-Alexandre Richard, Charles M. Marson 2016

机译：Domino Michael-aldol用于立体控制合成的双环3.3.1壬烷和双环3.2.1辛烷衍生物
8. Organotransition-Metal Metallacarboranes. 20(1) Fluoride-Catalyzed C-Si BondCleavage in Cp-Co(Me3Si)2C2B4H4, Synthesis of Parent Cp-CoC2B4H6 and Conversion to C-Substituted Cp-CoRR'C2B4H4 Derivatives [R] . Beavenuto, M. A., Grimes, R. N. 1991

机译：有机过渡 - 金属金属碳硼烷。 20（1）氟化物催化的Cp-Co（me3si）2C2B4H4中的C-si键断裂，母体Cp-CoC2B4H6的合成和转化为C-取代的Cp-CoRR'C2B4H4衍生物

SYNTHESIS OF BICYCLO[3.2.1]-OCTANONE DERIVATIVES BY METAL CATALYZED DECOMPOSITION OF ALPHA-DIAZOMETHYLKETONES

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