Synthesis of Ag(I) and Cu(I) Complexes with 4-Amino-5-Methyl-2h-1,2,4-Triazole-3(4h)-Thione Ligand as Thiocarbohydrazide Derivatives and their Antimicrobial Activity

Ghaneian Mohammad Taghi; Tabatabaee Masoumeh; Ehrampoush Mohammad Hassan; Jebali Ali; Hekmatimoghaddam Seyedhossein; Fallahzadeh Hossin; Fallahzadeh Reza Ali

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Synthesis of Ag(I) and Cu(I) Complexes with 4-Amino-5-Methyl-2h-1,2,4-Triazole-3(4h)-Thione Ligand as Thiocarbohydrazide Derivatives and their Antimicrobial Activity

机译：具有4-氨基-5-甲基-2h-1,2,4-三唑-3（4h）-亚硫基配体作为硫代碳酰肼衍生物的Ag（I）和Cu（I）配合物的合成及其抗菌活性

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The antimicrobial activity of 4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione (AMTT) and its silver(I) and copper(I) complexes has been investigated. Results show that MIC50 and MIC90 of the organic ligand against all test strains were higher than MIC50 and MIC90 of both complexes. The minimum MIC50 of the silver complex, copper complex, and the ligand against Candida albicans and Aspergillus niger were 5.6, 10.3, and 12.5 mu g/mL, respectively. The MIC50 and MIC90 of the silver complex were lower than those of the copper complex against Candida albicans, Aspergillus niger, Escherichia coli, and Pseudomonas aeruginosa. At the same time, the MIC50 of the silver complex is higher than that of the copper complex against Staphylococcus aureus.

机译：研究了4-氨基-5-甲基-2H-1,2,4-三唑-3（4H）-硫酮（AMTT）及其银（I）和铜（I）配合物的抗菌活性。结果表明，针对所有测试菌株的有机配体的MIC50和MIC90均高于两种复合物的MIC50和MIC90。银复合物，铜复合物和白色念珠菌和黑曲霉的配体的最低MIC50分别为5.6、10.3和12.5μg/ mL。对于白色念珠菌，黑曲霉，大肠杆菌和铜绿假单胞菌，银配合物的MIC50和MIC90低于铜配合物。同时，银配合物对金黄色葡萄球菌的MIC50高于铜配合物。

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来源
《Pharmaceutical Chemistry Journal》 |2015年第3期|共3页
作者
Ghaneian Mohammad Taghi; Tabatabaee Masoumeh; Ehrampoush Mohammad Hassan; Jebali Ali; Hekmatimoghaddam Seyedhossein; Fallahzadeh Hossin; Fallahzadeh Reza Ali;
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正文语种 eng
中图分类药学;
关键词
Thiocarbohydrazide; N; S donor ligand; Ag (I) complex; Cu(I) complex; antimicrobial activity;

机译：硫代碳酰肼;N;S供体配体;Ag（I）配合物;Cu（I）配合物;抗菌活性;

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1. Synthesis of Ag(I) and Cu(I) Complexes with 4-Amino-5-Methyl-2h-1,2,4-Triazole-3(4h)-Thione Ligand as Thiocarbohydrazide Derivatives and their Antimicrobial Activity [J] . Ghaneian Mohammad Taghi, Tabatabaee Masoumeh, Ehrampoush Mohammad Hassan, Pharmaceutical Chemistry Journal . 2015,第3期

机译：具有4-氨基-5-甲基-2h-1,2,4-三唑-3（4h）-亚硫基配体作为硫代碳酰肼衍生物的Ag（I）和Cu（I）配合物的合成及其抗菌活性
2. Synthesis, characterization, and crystal structure of the new Schiff-bases derived from 1,2,4-triazole and the structure of [(PPh3)(2)Cu(AMTT)NO3 center dot EtOH (AMTT=4-amino-5-methyl-2H-1,2,4-triazole-3(4H)-thione) [J] . Heshmatpour F, Ghassemzadeh M, Semsarha M, Zeitschrift fur Anorganische und Allgemeine Chemie . 2007,第3期

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Synthesis of Ag(I) and Cu(I) Complexes with 4-Amino-5-Methyl-2h-1,2,4-Triazole-3(4h)-Thione Ligand as Thiocarbohydrazide Derivatives and their Antimicrobial Activity

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