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首页> 外文期刊>Physica status solidi, B. Basic research >Amorphous thin films in the gallium-chalcogen system
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Amorphous thin films in the gallium-chalcogen system

机译:镓硫族元素体系中的非晶薄膜

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Thin amorphous films based on gallium-chalcogen (Ga-Ch), namely Ga2S3, Ga2Se3, Ga2Te3, and GaTe have been prepared by pulsed laser deposition (PLD). The films were characterized by X-ray diffraction, extended X-ray absorption fine structure (EXAFS), energy-dispersive X-ray spectroscopy (EDX), optical transmission spectroscopy, ellipsometry, and electrical measurements. Structural measurements showed that Ga is threefold coordinated, except the Te-based alloys were, it seems, only twofold coordinated, while the chalcogen is usually twofold coordinated. In all the compositions, layered and chain-like structures are assumed. The bandgaps range between 1.09 eV for Ga2Te3 and 2.21 eV for Ga2Se3. (C) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
机译:已经通过脉冲激光沉积(PLD)制备了基于镓-硫属元素(Ga-Ch)的非晶薄膜,即Ga 2 S 3,Ga 2 Se 3,Ga 2 Te 3和GaTe。膜的特征在于X射线衍射,扩展X射线吸收精细结构(EXAFS),能量色散X射线光谱法(EDX),光学透射光谱法,椭圆偏振法和电学测量。结构测量表明,Ga是三重配位的,除了Te基合金似乎只有二重配位的,而硫族元素通常是二重配位的。在所有组合物中,假定为层状和链状结构。 Ga2Te3的带隙范围为1.09 eV,Ga2Se3的带隙范围为2.21 eV。 (C)2016 WILEY-VCH Verlag GmbH&Co.KGaA,魏因海姆

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