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Entropy, entropy flux and entropy rate of granular materials

机译:颗粒材料的熵,熵通量和熵率

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The aim of this work is to analyze the entropy, entropy flux and entropy rate of granular materials within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas that follows from the Boltzmann equation differs from the one of a simple fluid due to the presence of a term which can be identified as the entropy density rate. From the knowledge of a non-equilibrium distribution functionvalid for processes closed to equilibriumit is obtained that the entropy density rate is proportional to the internal energy density rate divided by the temperature, while the entropy flux is equal to the heat flux vector divided by the temperature. A thermodynamic theory of a granular material is also developed whose objective is the determination of the basic fields of mass density, momentum density and internal energy density. The constitutive laws are restricted by the principle of material frame indifference and by the entropy principle. Through the exploitation of the entropy principle with Lagrange multipliers, it is shown that the results obtained from the kinetic theory for granular gases concerning the entropy density rate and entropy flux are valid in general for processes close to equilibrium of granular materials, where linearized constitutive equations hold.
机译:这项工作的目的是在玻尔兹曼方程和连续热力学的框架内分析粒状材料的熵,熵通量和熵率。结果表明,由于存在可被识别为熵密度率的项,因此遵循玻耳兹曼方程的粒状气体的熵不等式不同于简单流体中的一种。从对平衡接近的过程有效的非平衡分布函数的知识得知,熵密度比率与内部能量密度比率除以温度成正比,而熵通量等于热通量矢量除以温度。还发展了粒状材料的热力学理论,其目的是确定质量密度,动量密度和内部能量密度的基本场。本构定律受物质框架无关性原理和熵原理的限制。通过利用拉格朗日乘数研究熵原理,表明从粒状气体动力学理论得出的关于熵密度率和熵通量的结果通常对接近粒状材料平衡的过程有效,其中线性本构方程保持。

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