Synthesis and Characterization of Tetraphenylporphyrinate Manganese(III) Siloxides by Silyl Group Transfer from Silanethiols

机译：硅烷硫醇甲硅烷基转移的四苯基晶锰（III）硅烷酯的合成与表征

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The synthesis of the first examples of siloxide-containing Mn(III) porphyrinates has been accomplished via a novel silyl group transfer from sulfur to oxygen. Investigations into the pathway of formation of the siloxide complexes suggest that initial reduction of Mn(III) by the silanethiols produces [Mn~(II)(TPP)], which reacts with oxygen in the presence of (R_3Si)_2S_2 to afford the siloxide complexes. Solid-state structures of the complexes confirm the Mn-O linkage with short distances of 1.92 A. Characterization of the complexes was made possible using APCI. This use of APCI represents the first successful application of mass spectrometry to unambiguously identify oxygen-bound manganese porphyrinates.

机译：通过从硫至氧的新甲硅烷基转移完成，通过从氧气的新甲硅烷基转移完成，完成含硅氧烷的Mn（III）卟啉卟啉的第一实例的合成。对硅氧烷复合物形成途径的研究表明，硅硫醇的初始降低Mn（III）产生[Mn〜（II）（TPP）]，其在（R_3Si）_2S_2存在下与氧化物的作用反应得到硅氧化物复合物。复合物的固态结构证实了与1.92A的短距离的Mn-O键合。使用APCI使配合物的表征成为可能。这种APCI的使用代表了质谱法以明确鉴定氧结合锰卟啉酸盐的第一个成功应用。

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《ASMS Conference on Mass Spectrometry and Allied Topics》|2016年|1CD|共1页
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Zachary J. Tonzetich; Daniel J. Meininger; Zieph Kasrawi; Hadi D. Arman; Wendell P. Griffith;
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1. Synthesis of tetraphenylporphyrinate manganese(III) siloxides by silyl group transfer from silanethiols [J] . Meininger Daniel J., Kasrawi Zieph, Arman Hadi D., Journal of Coordination Chemistry . 2016,第11a13期

机译：硅烷硫醇的甲硅烷基转移合成四苯基卟啉酸酯锰（III）氧化物
2. Di(mu-oxo) binuclear manganese(III,IV) poly(bipyridyl) complexes bearing four ruthenium(II) photoactive units: Synthesis, characterization, and photoinduced electron-transfer properties [J] . Romain S, Lepretre JC, Chauvin J, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第7期

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机译：硅烷硫醇甲硅烷基转移的四苯基晶锰（III）硅烷酯的合成与表征
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机译：过渡金属氧代（Hydroxo）氧化硅的合成和结构表征：过渡金属二烷基酰胺与二苯基硅烷二醇的反应

Synthesis and Characterization of Tetraphenylporphyrinate Manganese(III) Siloxides by Silyl Group Transfer from Silanethiols

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