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Microstructure of precipitated Au Nanoclusters in Single Crystal MgO

机译:单晶MgO中沉淀的Au纳米能器的微观结构

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Gold nanoclusters dispersed in single crystal MgO were prepared by ion implantation and subsequent annealing at 1000 deg C.The morphological feature,size,crystallographic orientation of the Au nanoclusters with respect to the MgO matrix,and the interface structure between the Au nanoclusters and MgO were investigated using transmission electron microscopy.During annealing,the Au clustres nucleate coherently in the MgO lattice,leading to an epitaxial orientation relationship of [010]_(MgO)//[010]_Au and (200)_(MgO)//(200)_Au that is maintained for all the Au clusters.A critial size for the coherent-semicoherent interface transition is observed to be in the range from approx 5 to 8 nm for Au clusters in MgO.Au clusters larger than this critical size exhibit faceting on the {001} planes.The precipitated Au also exhibits internal dislcoations.
机译:通过离子注入和随后的1000℃的后续退火制备分散在单晶MgO中的金纳中纳米蛋白。形态学特征,尺寸,Au纳米团簇相对于MgO基质的晶体取向,以及Au纳米团和MgO之间的界面结构使用透射电子显微镜进行研究。用辐射退火,Au隧道在MgO格子中连贯成核,导致[010] _(MgO)// [010] _au和(200)_(MgO)//(MgO)//( 200)维持所有Au簇的_au。观察到的相干 - 半界面过渡的批判大小为MgO.au集群中的Au簇的大约5至8nm的范围内大小表现出刻面在{001}平面上。沉淀的Au也表现出内部脱果。

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