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Production of Some Chemically Modified Adsorbents from Some Field Crops by- Products to Reduce Ochratoxin A

机译:从一些田间作物副产物生产某些化学改性的吸附剂以减少O曲霉毒素A

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This study aimed to produce some chemically modified adsorbents (CMA) from some field crops by- products to reduce ochratoxin A (OTA). Chemical modification was performed on broken rice starch, soybean hulls, and wheat bran to produce acetylated rice starch (ARS 8, ARS 16%), modified soybean hulls (MSH), and micronized wheat bran (MWB). The presence of the new functional groups due to chemical modification was checked via Fourier Transform Infrared Spectroscopy (FTIR) method. The incidence of OTA in four types of commercial apple juice samples was studied. The efficacy of the chemically modified adsorbents (CMA) for reducing OTA at 500 and 1000 mg was tested via HPLC method and applied at contaminated apple juice samples. From FTIR different stretching bonds and new functional groups at different band positions relates to chemical modification were detected. MSH, MWB, ARS 8% and ARS 16% at 500 and 1000 mg were reduced OTA spiked solution by (73.2, 82.7); (79.5, 84.03); (66.5, 72.0), and (70.9, 75.8)%, respectively. The total number of contaminated apple juice samples with OTA was 33 out of 150, and 13 of them exceeded the permissible limits of the EU. The reduction of OTA in all contaminated apple juice samples using CMA was 100%, and the treated samples were highly acceptable by the panelists, and there were no significant changes in appearance, color, and flavor. The results of this study could be useful in utilizing broken rice, soybean hulls, and wheat bran; improving their adsorption capacities via chemical modification with acids and delivering highly reactive adsorbents to the food processors to produce safe food and remove OTA from contaminated apple juice.
机译:这项研究旨在从一些大田作物副产品中生产一些化学改性的吸附剂(CMA),以减少曲毒素A(OTA)。对破碎的大米淀粉,大豆壳和麦麸进行化学改性,以生产乙酰化大米淀粉(ARS 8,ARS 16%),改性大豆壳(MSH)和微粉化的麦麸(MWB)。通过傅立叶变换红外光谱(FTIR)方法检查了由于化学修饰而导致的新官能团的存在。研究了四种类型的商业苹果汁样品中OTA的发生率。通过HPLC方法测试了化学改性吸附剂(CMA)在500和1000 mg下减少OTA的功效,并应用于受污染的苹果汁样品。从FTIR检测到不同的拉伸键和与化学修饰相关的不同能带位置的新官能团。 MSH,MWB,ARS 8%和ARS 16%在500和1000 mg下的OTA加标溶液减少了(73.2,82.7); (79.5,84.03); (66.5、72.0)和(70.9、75.8)%。在150个样品中,OTA污染的苹果汁样品总数为33,其中13个样品超过了欧盟的允许限值。使用CMA,所有受污染的苹果汁样品中的OTA降低了100%,并且经过处理的样品被专家们高度接受,并且外观,颜色和风味没有明显变化。这项研究的结果可能有助于利用碎米,大豆壳和麦麸。通过用酸进行化学修饰来提高其吸附能力,并向食品加工商提供高反应性的吸附剂,以生产安全的食品并从受污染的苹果汁中去除OTA。

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