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Effect of Dry- and Wet-Milling Processes on Chemical, Physicochemical Properties and Starch Molecular Structures of Rice Starches

机译:干磨和湿磨工艺对大米淀粉化学,理化性质和淀粉分子结构的影响

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摘要

Rice starches from low amylose (Pathum Thani 1), medium amylose (RD 7) and high amylose (Leuang 11) varieties prepared from dry- and wet-milling processes were investigated. Dry-milled rice starches contained significantly (p < 0.05) higher amounts of damaged starch than wet-milled rice starches in all rice varieties. The scanning electron micrographs (SEM) of starch granules confirmed that damaged starches occurred from the dry-milling process more than from the wet-milling process. The enthalpy required to gelatinize dry-milled rice starches (8.11-9.53 J/g) from all rice varieties was significantly (p < 0.05) lower than those of wet-milled rice starches (9.24-12.48 J/g). The peak viscosity (257.75-353.80 RVU) rnand final viscosity (248.64-391.00 RVU) of dry-milled rice starches measured by Rapid Visco Analyser (RVA) were significantly (p < 0.05) lower than those of wet-milled rice starches. Rice starch molecular weight distributions obtained by size-exclusion chromatography with RI and multi-angle laser light scattering detection (SEC-RI-MALLS) showed that dry-milled rice starch samples contained lower amounts of the high molecular weight portion of starch (amylopectin) than wet-milled samples. The molecular weight of both amylopectin from dry-milled rice starches (0.95-1.7 x 10~7 Da) was lower than that of wet-milled rice starches (1.11-1.90 x 10~7 Da), suggesting that the dry-milling process caused a higher degree of starch fragmentation than the wet-milling process.
机译:研究了通过干磨和湿磨工艺制备的低直链淀粉(Pathum Thani 1),中直链淀粉(RD 7)和高直链淀粉(Leuang 11)的大米淀粉。在所有水稻品种中,干磨米淀粉所含的受损淀粉量均显着高于(p <0.05)湿磨米淀粉。淀粉颗粒的扫描电子显微照片(SEM)证实,与干法相比,干法研磨产生的淀粉受损更多。使所有大米品种的干磨米淀粉糊化所需的焓(8.11-9.53 J / g)显着(p <0.05)低于湿磨米淀粉(9.24-12.48 J / g)。通过快速粘度分析仪(RVA)测定的干磨米淀粉的峰值粘度(257.75-353.80 RVU)和最终粘度(248.64-391.00 RVU)显着(p <0.05)低于湿磨米淀粉的峰值(p <0.05)。通过具有RI的尺寸排阻色谱和多角度激光散射检测(SEC-RI-MALLS)获得的大米淀粉分子量分布表明,干磨的大米淀粉样品中淀粉(支链淀粉)的高分子量部分含量较低。比湿磨样品。干磨米淀粉中的两种支链淀粉的分子量(0.95-1.7 x 10〜7 Da)均低于湿磨米淀粉(1.11-1.90 x 10〜7 Da)的分子量,表明干磨过程引起的淀粉破碎程度高于湿磨过程。

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