Gold(I)-Catalyzed Synthesis of Highly Substituted 2-Cyclopentenones from 5-Siloxypent-3-en-1-ynes

Sang Eun An; Jihee Jeong; Baburaj Baskar; Joopyung Lee; Junho Seo; Young Ho Rhee

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Gold(I)-Catalyzed Synthesis of Highly Substituted 2-Cyclopentenones from 5-Siloxypent-3-en-1-ynes

机译：金（I）催化从5-硅烷氧基戊-3-烯-1-炔的合成高度取代的2-环戊烯酮

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摘要

Intramolecular addition of nucleophiles to the Lewis acid activated alkynes represents one of the most powerful strategies for the synthesis of cyclic compounds

机译：分子内向路易斯酸活化的炔烃中添加亲核试剂是合成环状化合物的最有力策略之一

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来源
《Chemistry: A European journal》 |2009年第44期|共5页
作者
Sang Eun An; Jihee Jeong; Baburaj Baskar; Joopyung Lee; Junho Seo; Young Ho Rhee;
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正文语种 eng
中图分类应用化学;
关键词
Synthesis; Cyclopentenones; nucleophiles;

机译：合成;环戊烯酮;亲核试剂;

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专利

1. Gold(I)-Catalyzed Synthesis of Highly Substituted 2-Cyclopentenones from 5-Siloxypent-3-en-1-ynes [J] . Sang Eun An, Jihee Jeong, Baburaj Baskar, Chemistry: A European journal . 2009,第44期

机译：金（I）催化从5-硅烷氧基戊-3-烯-1-炔的合成高度取代的2-环戊烯酮
2. Gold(I)-catalyzed, highly diastereoselective, tandem heterocyclizations/ [3+2] cycloadditions: Synthesis of highly substituted cyclopenta[c]furans [J] . Gao H., Wu X., Zhang J. Chemistry: A European journal . 2011,第10期

机译：金（I）催化的，高度非对映选择性的串联杂环化/ [3 + 2]环加成反应：高度取代的环戊[c]呋喃的合成
3. Ming-Phos/Gold(I)-Catalyzed Stereodivergent Synthesis of Highly Substituted Furo3,4-d1,2oxazines [J] . Lujia Zhou, Bing Xu, Danting Ji, 中国化学（英文版） . 2020,第006期

机译：Ming-Phos / Gold（I）催化立体异构合成高取代度的呋喃3,4-d 1,2恶嗪
4. Ruthenium- and Gold-Catalyzed Tandem Reaction: Synthesis of Substituted Oxazoles from Propargylic Alcohols and Amides [C] . Marilyn Daisy Milton, Youichi Inada, Yoshiaki Nishibayashi, Symposium on Organometallic Chemistry . 2004

机译：钌和金催化串联反应：从丙基醇和酰胺的合成取代的恶唑
5. Part I: Total Synthesis of (+/-)-Pallambins C and D, and, Part II: Gold-Catalyzed Tandem Cyclization towards Substituted Bicyclo[3.2.1]Octenone Derivatives: Lead to Total Synthesis of Dhilirolides A-D. [D] . Xu, Xuesong. 2013

机译：第一部分：（+/-）-戊二烯C和D的全合成，第二部分：金催化的串联环化反应取代双环[3.2.1]大黄酮衍生物：导致Dhilirolides A-D的全合成。
6. Gold(I)-Catalyzed Intermolecular Cycloaddition ofAllenamides with αβ-Unsaturated Hydrazones: EfficientAccess to Highly Substituted Cyclobutanes [O] . Paloma Bernal-Albert, Hélio Faustino, Ana Gimeno, -1

机译：金（I）催化的分子间环加成反应具有αβ-不饱和Hy的烯丙酰胺：有效获得高度取代的环戊二烯
7. Inside Back Cover: A Gold(I)-Catalyzed Domino Coupling of Alcohols with Allenes Enables the Synthesis of Highly Substituted Indenes (Chem. Eur. J. 41/2016) [O] . Alexander Preinfalk, Antonio Misale, Nuno Maulide 2016

机译：内部后盖：黄金（i） - 用艾伦醇的醇类催化偶联能够合成高度取代的茚（Chem.Eur。J. 41/2016）

Gold(I)-Catalyzed Synthesis of Highly Substituted 2-Cyclopentenones from 5-Siloxypent-3-en-1-ynes

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