Synthesis of 2,8-Dioxaspiro[4,5]decane-1,3,7,9-tetrone and the Reactions with Amines

Jun Kato; Atsushi Seo; Kazuki Kiso; Kazuaki Kudo; Shinsaku Shiraishi

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Synthesis of 2,8-Dioxaspiro[4,5]decane-1,3,7,9-tetrone and the Reactions with Amines

机译：2,8-二氧杂螺[4,5]癸烷-1,3,7,9-四元的合成及与胺的反应

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For the studies of highly-sophisticated utilization of itaconic anhydride, some compounds of polybasic carboxylic acids having a quaternary a spiro carbon atom were prepared, starting from itaconic anhydride and isoprene. Aliphatic tetracarboxylic dianhydride having a spiro carbon atom with five- and six-membered rings, 2,8-dioxaspiro[4,5]decane-1,3,7,9-tetrone(TCDA), was also obtained. The reaction of TCDA with primary amines and subsequent dehydration gave two types of products, either diimides or imide (with five-membered ring)-anhydrides (with six-membered ring), depending on the hydrocarbon moiety of the amines used. It was suggested that each imide-anhydride was formed by the intramolecular ring transformation of the intermediate amic acid-anhydride.

机译：为了研究衣康酸酐的高度复杂的利用，从衣康酸酐和异戊二烯开始，制备了具有季碳原子和螺碳原子的多元羧酸的一些化合物。还获得了具有螺环碳原子和五元和六元环的脂肪族四羧酸二酐，2,8-二氧杂螺[4,5]癸烷-1,3,7,9-四极（TCDA）。 TCDA与伯胺的反应以及随后的脱水反应产生了两种类型的产物，即二酰亚胺或酰亚胺（具有五元环）-酸酐（具有六元环），具体取决于所用胺的烃部分。提示每种酰亚胺酐是通过中间体酰胺酸酐的分子内环转化形成的。

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《Bulletin of the Chemical Society of Japan》 |1999年第5期|共7页
作者
Jun Kato; Atsushi Seo; Kazuki Kiso; Kazuaki Kudo; Shinsaku Shiraishi;
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中图分类化学;化学工业;
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1. Synthesis of 2,8-Dioxaspiro[4,5]decane-1,3,7,9-tetrone and the Reactions with Amines [J] . Jun Kato, Atsushi Seo, Kazuki Kiso, Bulletin of the Chemical Society of Japan . 1999,第5期

机译：2,8-二氧杂螺[4,5]癸烷-1,3,7,9-四元的合成及与胺的反应
2. Flexible synthesis of enantiomerically pure 2,8-dialkyl-1,7-dioxaspiro[5.5]undecanes and 2,7-dialkyl-1,6-dioxaspiro[4.5]decanes from propargylic and homopropargylic alcohols [J] . Schwartz BD, Hayes PY, Kitching W, The Journal of Organic Chemistry . 2005,第8期

机译：从炔丙醇和高炔丙醇灵活合成对映体纯的2,8-二烷基-1,7-二氧杂螺[5.5]十一烷和2,7-二烷基-1,6-二氧杂螺[4.5]癸烷
3. NEW ONE-STEP PROCESS FOR THE SYNTHESIS OF FUNCTIONALIZED 1,6-DIOXASPIRO[4,5]DECANES [J] . Carretero JC., Diaz N., Hamdouchi C., Tetrahedron . 1995,第31期

机译：功能性1,6-二氧杂螺环[4,5]癸烷的合成新一步法
4. SYNTHESIS OF THE OPTICALLY ACTIVE FORMS OF 4,10-DIHYDROXY-1,7-DIOXASPIRO 5,5 UNDECANE AND THEIR CONVERSION TO THE ENANTIOMERS OF 1,7-DIOXASPIRO5.5UNDECANE, THE OLIVE FLY PHEROMONE [C] . T. Uematsu, K.Mori International Congress of Pesticide Chemistry . 1986

机译：合成4,10-二羟基-1,7-Dioxaspiro 5,5的非甲烷的光学活性形式及其转化为1,7-二氧化硅的对映体5.5未甲烷，橄榄蝇信息素
5. Multicomponent reactions of allenyl and alkynyl boron derivatives with amines and aldehydes and their use in the synthesis of novel multifunctional amines and heterocycles [D] . Liepouri, Fotini 2007

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6. 13579111315-Octaazapentacyclo9.5.1.139.0618.01417octadecane-481216-tetrone monohydrate: a methylene-bridged glycoluril dimer [O] . Pei-Hua Ma, Xin Xiao, Yun-Qian Zhang, 2008

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机译：取代的1-甲基硫基-4,5-二氢1,2二硫醇3,4-C喹啉碘化物与芳基胺的反应。新型1,2-二硫醇3,4-C喹啉-1-少烯（芳基）胺和10-（芳基氨基）-7,10-二氢1,2二硫醇3,4-C吡咯的3,4-C吡咯3,2,1-IJ喹啉-4,5-致力
8. Synthesis of 4,5-Dihydrobenzo(b)Furans, 4,5-Dihydrobenzo(b)Thiophenes, and 4,5-Dihydroindoles Vacuum Pyrolysis - Electrocyclic Reactions. [R] . Rosen, B. I., Weber, W. P. 1976

机译：4,5-二氢苯并（b）呋喃，4,5-二氢苯并（b）噻吩和4,5-二氢吲哚的合成真空热解 - 电环反应。

Synthesis of 2,8-Dioxaspiro[4,5]decane-1,3,7,9-tetrone and the Reactions with Amines

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