New Activators for the Coupling Reaction of Terminal Alkynes with Organic Halides

Mohamed S.Mohamed Ahmed; Akitoshi Sekiguchi; Tomohiro Shimada; Jun Kawashima; Atsunori Mori

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New Activators for the Coupling Reaction of Terminal Alkynes with Organic Halides

机译：末端炔烃与有机卤化物偶联反应的新型活化剂

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Cross-coupling reactions of terminal alkynes with organic halides catalyzed by palladium(0)or palladium(0)/Cu(I)take place in the presence of several activators,such as silver(I)oxide,tetrabutylammonium fluoride(TBAF),and tet-rabutylammonium hydroxide(TBAOH),to give the corresponding coupling products in good-to-excellent yields.

机译：钯（0）或钯（0）/ Cu（I）催化的末端炔烃与有机卤化物的交叉偶联反应在几种活化剂的存在下发生，例如氧化银（I），氟化四丁基铵（TBAF）和叔丁基氢氧化铵（TBAOH），以良好至优异的产率得到相应的偶联产物。

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《Bulletin of the Chemical Society of Japan》 |2005年第2期|共4页
作者
Mohamed S.Mohamed Ahmed; Akitoshi Sekiguchi; Tomohiro Shimada; Jun Kawashima; Atsunori Mori;
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正文语种 eng
中图分类化学;
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专利

1. New Activators for the Coupling Reaction of Terminal Alkynes with Organic Halides [J] . Mohamed S.Mohamed Ahmed, Akitoshi Sekiguchi, Tomohiro Shimada, Bulletin of the Chemical Society of Japan . 2005,第2期

机译：末端炔烃与有机卤化物偶联反应的新型活化剂
2. A highly effective Pd/Cu-catalyzed coupling reaction of terminal alkynes with organic halides promoted by tetrabutylammonium fluoride or hydroxide [J] . Mori A., Kondo T., Sekiguchi A., Synlett . 2001,第5期

机译：四丁基铵氟化物或氢氧化物促进的末端炔烃与有机卤化物的高效钯/铜催化偶联反应
3. A Copper‐Catalyzed Sonogashira Coupling Reaction of Diverse Activated Alkyl Halides with Terminal Alkynes Under Ambient Conditions [J] . Advanced synthesis & catalysis . 2020,第11期

机译：在环境条件下与末端醇酸酯不同活化烷基卤化物的铜催化的Sonogashira偶联反应
4. Ni-Catalyzed Regioselective Three-Component Coupling Reaction of Terminal Alkynes, Alkyl Halides, and Grignard Reagents [C] . Fumiaki Bando, Jun Terao, Nobuaki Kambe Symposium on Organometallic Chemistry . 2008

机译：Ni催化末端炔烃，烷基卤化物和格氏试剂的三组分偶联反应
5. Development of Group 4 Metallocene/Palladium Bimetallic-Catalyzed Reductive Cross-Coupling Reaction between Alkynes and Aryl Halides [D] . 髙橋　慶多 2019

机译：炔烃与芳基卤化物之间第4族茂金属/钯双金属催化的还原交叉偶联反应的研究
6. Regioselective Formation of α-Vinylpyrroles from the Ruthenium-Catalyzed Coupling Reaction of Pyrroles and Terminal Alkynes Involving C–H Bond Activation [O] . Ruili Gao, Chae S. Yi -1

机译：从吡咯和末端炔烃的钌催化偶联反应涉及C-H键活化α-乙烯基吡咯的区域选择性形成
7. A Synthesis of (E)-(1-Organo-1-alkenyl)boronates by the Palladium-Catalyzed Cross-Coupling Reaction of (E)-1,2-Bis(boryl)-1-alkenes with Organic Halides- A Formal Carboboration of Alkynes via the Diboration-Coupling Sequence. [O] . Ishiyama Tatsuo, Yamamoto Masafumi, Miyaura Norio 1996

机译：（E）-1,2-双（硼基）-1-烯烃与有机卤化物的钯催化交叉偶联反应合成（E）-（1-Organo-1-alkenyl）硼酸酯通过Diboration-Coupling序列制备炔烃。

New Activators for the Coupling Reaction of Terminal Alkynes with Organic Halides

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