Reaction of the N-mesylates of 1,3a,4,8b-tetrahydrocyclopenta[b]indoles and 3,4,4a,9a-tetrahydrocarbazoles with dimethyldioxirane and bromine

R. R. Gataullin; R. R. Ishberdina; A. V. Antipin; K. Yu. Suponitskii; N. N. Kabal’nova; O. V. Shitikova; L. V. Spirikhin; M. Yu. Antipin; I. B. Abdrakhmanov

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Reaction of the N-mesylates of 1,3a,4,8b-tetrahydrocyclopenta[b]indoles and 3,4,4a,9a-tetrahydrocarbazoles with dimethyldioxirane and bromine

机译：1,3a，4,8b-四氢环戊[b]吲哚和3,4,4a，9a-四氢咔唑的N-甲磺酸酯与二甲基二环氧乙烷和溴的反应

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In reaction with dimethyldioxirane N-mesyl-1,3a,4,8b-tetrahydrocyclopenta[b]indoles and N-mesyl-3,3,4a,9a-tetrahydrocarbazoles mostly form the trans-epoxide. The reaction with molecular bromine leads to the product from halogenation in the aromatic ring, i.e., the corresponding N-mesyl-7-bromo-1,3a,4,8b-tetrahydrocyclopenta[b]indole or N-mesyl-6-bromo-3,4,4a,9a-tetrahydrocarbazole.

机译：与二甲基二环氧乙烷反应时，N-甲磺酰基-1,3a，4,8b-四氢环戊[b]吲哚和N-甲磺酰基-3,3,4a，9a-四氢咔唑主要形成反式环氧化物。与分子溴的反应导致芳香环中的卤化产物产生，即相应的N-甲酰基-7-溴-1,3a，4,8b-四氢环戊[b]吲哚或N-甲酰基-6-溴- 3,4,4a，9a-四氢咔唑

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来源
《Chemistry of heterocyclic compounds》 |2006年第9期|共7页
作者
R. R. Gataullin; R. R. Ishberdina; A. V. Antipin; K. Yu. Suponitskii; N. N. Kabal’nova; O. V. Shitikova; L. V. Spirikhin; M. Yu. Antipin; I. B. Abdrakhmanov;
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正文语种 eng
中图分类杂环化合物;
关键词
dimethyldioxirane; tetrahydrocarbazoles; tetrahydrocyclopentabindoles; X-ray crystallographic analysis;

机译：二甲基二环氧乙烷;四氢咔唑;四氢环戊[b]吲哚;X射线晶体学分析;

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1. Reaction of the N-mesylates of 1,3a,4,8b-tetrahydrocyclopenta[b]indoles and 3,4,4a,9a-tetrahydrocarbazoles with dimethyldioxirane and bromine [J] . R. R. Gataullin, R. R. Ishberdina, A. V. Antipin, Chemistry of heterocyclic compounds . 2006,第9期

机译：1,3a，4,8b-四氢环戊[b]吲哚和3,4,4a，9a-四氢咔唑的N-甲磺酸酯与二甲基二环氧乙烷和溴的反应
2. Synthesis of 7-Bromo, 7-Phenylethynyl, 7-Azido, and 7-Nitro Derivatives of N-Acetyl-1,3a,4,8b-tetrahydrocyclopenta[b]indole [J] . D. A. Skladchikov, A. A. Fatykhov, R. R. Gataullin Russian Journal of Organic Chemistry . 2014,第1期

机译：N-乙酰基-1,3a，4,8b-四氢环戊[b]吲哚的7-溴，7-苯基乙炔基，7-叠氮基和7-硝基衍生物的合成
3. Unexpected epoxidation product in oxidation of N-tosyl-7-methoxy-1,3a,4,8b-tetrahydrocyclopenta[b]indole with potassium permanganate [J] . Gataullin RR, Suponitsky KY Mendeleev Communications . 2009,第5期

机译：高锰酸钾氧化N-甲苯磺酰基-7-甲氧基-1,3a，4,8b-四氢环戊[b]吲哚中的意外环氧化产物
4. Rearrangement and fragmentation reactions of different estrogen and indole ethers: New aspects found with a FT-ICR [C] . Christoph Freudenhammer, Jurgen Grotemeyer American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2010

机译：不同雌激素和吲哚醚的重排和分散反应：用FT-ICR发现的新方面
5. Studies on multicomponent reactions: New 4- and 5-component routes to aminoacid diamides and 3-component routes to substituted indoles by modification of the classical Ugi and Fischer indole reactions. [D] . Simoneau, Christopher Allen. 2007

机译：多组分反应的研究：通过改良经典的Ugi和Fischer吲哚反应，新的4和5组分途径可生成氨基酸二酰胺，而3组分途径可生成取代的吲哚。
6. Application of 67-Indole Aryne Cycloaddition and Pd(0)-Catalyzed Suzuki-Miyaura and Buchwald-Hartwig Cross-Coupling Reactions for the Preparation of Annulated Indole Libraries [O] . Paul D. Thornton, Neil Brown, David Hill, -1

机译：67-Indole Aryne环加成和PD（0）的应用 - 催化Suzuki-Miyaura和Buchwald-Hartwig交叉偶联反应用于制备子弹吲哚文库
7. Vilsmeier-Haack-Arnold and Bromination Reactions of 4H-Pyrazolo(1,5-a)indole Derivatives. [O] . Jing-Kang SHEN, Hajime KATAYAMA, Noriyuki TAKATSU 1994

机译：vilsmeier-haack-arnold和4h-pyrozolo（1,5-a）吲哚衍生物的溴化反应。
8. Reaction of E,1,4-poly(2-triethylsilyl-1,3-butadiene) with Bromine. Stereoselective Synthesis of Z-1,4-poly(2-bromo-1,3-butadiene) [R] . Jiang, W., Weber, W. P. 1988

机译：E，1,4-聚（2-三乙基甲硅烷基-1,3-丁二烯）与溴的反应。立体选择性合成Z-1,4-聚（2-溴-1,3-丁二烯）

Reaction of the N-mesylates of 1,3a,4,8b-tetrahydrocyclopenta[b]indoles and 3,4,4a,9a-tetrahydrocarbazoles with dimethyldioxirane and bromine

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