Two coordination polymers constructed from pillared M-O (M = Na~+ or Ba~(2+)) subunits with 3-formyl-4-hydroxybenzenesulfonic acid as ligand

Li S.-N.; Zhai Q.-G.; Hu M.-C.; Jiang Y.-C.

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Two coordination polymers constructed from pillared M-O (M = Na~+ or Ba~(2+)) subunits with 3-formyl-4-hydroxybenzenesulfonic acid as ligand

机译：由有柱状的M-O（M = Na〜+或Ba〜（2+））亚基与3-甲酰基-4-羟基苯磺酸作为配体构造的两种配位聚合物

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Two new coordination polymers, [Na(H_2L)(H_2O) _2]_n (1) and [Ba(H_2L)_2(H _2O)_n (2) (H_3L = 3-formyl-4- hydroxybenzenesulfbnic acid) were synthesized and structurally characterized. The H2L~- ligand shows three different bridging modes, μ_3 in 1, μ_3 and μ_4 in 2. Compound 1 presents a 2D pillared structure, whereas 2 forms a 3D framework. Both 1 and. 2 show blue luminescence at 380 nm in aqueous solution, however, their solid state emissions are at 406 and 446 nm, respectively.

机译：合成了两种新的配位聚合物[Na（H_2L）（H_2O）_2] _n（1）和[Ba（H_2L）_2（H _2O）_n（2）（H_3L = 3-甲酰基-4-羟基苯磺酸）表征。 H2L〜-配体显示三种不同的桥连模式：1、3中的μ_3和2中的μ_4。化合物1呈现2D柱状结构，而2形成3D骨架。 1和。图2显示了在水溶液中在380nm处的蓝色发光，然而，它们的固态发射分别在406nm和446nm处。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2010年第6期|共5页
作者
Li S.-N.; Zhai Q.-G.; Hu M.-C.; Jiang Y.-C.;
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正文语种 eng
中图分类化学;
关键词
Barium; Luminescence; Pillared subunits; Sodium; Sulfonates;

机译：钡;发光;柱状亚基;钠;磺酸盐;

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1. Two coordination polymers constructed from pillared M-O (M = Na~+ or Ba~(2+)) subunits with 3-formyl-4-hydroxybenzenesulfonic acid as ligand [J] . Li S.-N., Zhai Q.-G., Hu M.-C., Zeitschrift fur Anorganische und Allgemeine Chemie . 2010,第6期

机译：由有柱状的M-O（M = Na〜+或Ba〜（2+））亚基与3-甲酰基-4-羟基苯磺酸作为配体构造的两种配位聚合物
2. An unusual 3D pillared-layer cobalt(II) coordination polymer containing helical motifs and novel topology constructed from mixed ligands [J] . Guo-Ping Yang, Bin Liu, Lei Hou Inorganic Chemistry Communications . 2011,第6期

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Two coordination polymers constructed from pillared M-O (M = Na~+ or Ba~(2+)) subunits with 3-formyl-4-hydroxybenzenesulfonic acid as ligand

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