ON THE PREPARATION OF TETRAMETHYLAMMONIUM TRIFLUOROMETHYLBISTRIFLUOROMETHYLNITROXYLIODATE(I) (CH3)(4)N+(CF3)2NOICF(3)(-) AND THE REACTION OF TETRAMETHYLAMMONIUM BISTRIFLUOROMETHYLNITRATE (CH3)(4)N+(CF3)(2)NO- WITH CL-2 AND CLONO2 [German]

Minkwitz R.; Jakob J.

首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >ON THE PREPARATION OF TETRAMETHYLAMMONIUM TRIFLUOROMETHYLBISTRIFLUOROMETHYLNITROXYLIODATE(I) (CH3)(4)N+(CF3)2NOICF(3)(-) AND THE REACTION OF TETRAMETHYLAMMONIUM BISTRIFLUOROMETHYLNITRATE (CH3)(4)N+(CF3)(2)NO- WITH CL-2 AND CLONO2 [German]

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ON THE PREPARATION OF TETRAMETHYLAMMONIUM TRIFLUOROMETHYLBISTRIFLUOROMETHYLNITROXYLIODATE(I) (CH3)(4)N+(CF3)2NOICF(3)(-) AND THE REACTION OF TETRAMETHYLAMMONIUM BISTRIFLUOROMETHYLNITRATE (CH3)(4)N+(CF3)(2)NO- WITH CL-2 AND CLONO2 [German]

机译：甲基三氟甲基双氟甲基硝基氧肟酸（I）（CH3）（4）N +（CF3）2NOICF（3）（-）的制备及四甲基双氟甲基硝酸亚硝酸铵（CH3）（4）N-（CF3）的反应2 AND CLONO2 [德语]

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The preparation of (CF3)(2)NO- as tetramethylammoniumsalt and its addition reaction with CF3I are described. The formed Tetramethylammonium trifluoromethylbistrifluoromethylnitroxyliodate(I) (CH3)(4)N+(CF3)(2)NOICF3- is characterized by its spectra and the reaction with CF3OCl. In addition we present our approach to the preparation of (CF3)(2)NOCl by the reaction of (CH3)(4)N+(CF3)(2)NO- With Cl-2 and ClONO2. The thermolabile compounds have been characterized by i. r., Raman, F-19 and C-13 NMR spectra. [References: 28]

机译：描述了作为四甲基铵盐的（CF3）（2）NO-的制备及其与CF3I的加成反应。形成的四氟甲基三氟甲基双三氟甲基硝基氧肟酸酯（I）（CH3）（4）N +（CF3）（2）NOICF3-的光谱和与CF3OCl的反应进行了表征。此外，我们介绍了通过（CH3）（4）N +（CF3）（2）NO-与Cl-2和ClONO2反应制备（CF3）（2）NOCl的方法。热不稳定化合物的特征在于： r。，拉曼光谱，F-19和C-13 NMR光谱。 [参考：28]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第4期|共6页
作者
Minkwitz R.; Jakob J.;
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中图分类化学;
关键词
Tetramethylammonium bistrifluoromethylnitrate; Tetramethylammonium trinuoromethylbistrifluoromethylnitroxyliodate(i); Bistrifluoromethylnitroxyde; Vibrational spectra; F-19; c-13 nmr; Fluorocarbon derivatives; Raman-spectra; Nitrogen;

机译：二甲基三氟甲基铵四甲基铵;三氟甲基双三氟甲基硝基氧肟酸四甲基铵;

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1. ON THE PREPARATION OF TETRAMETHYLAMMONIUM TRIFLUOROMETHYLBISTRIFLUOROMETHYLNITROXYLIODATE(I) (CH3)(4)N+(CF3)2NOICF(3)(-) AND THE REACTION OF TETRAMETHYLAMMONIUM BISTRIFLUOROMETHYLNITRATE (CH3)(4)N+(CF3)(2)NO- WITH CL-2 AND CLONO2 [German] [J] . Minkwitz R., Jakob J. Zeitschrift fur Anorganische und Allgemeine Chemie . 1997,第4期

机译：甲基三氟甲基双氟甲基硝基氧肟酸（I）（CH3）（4）N +（CF3）2NOICF（3）（-）的制备及四甲基双氟甲基硝酸亚硝酸铵（CH3）（4）N-（CF3）的反应2 AND CLONO2 [德语]
2. Preparation of tetramethylammonium azidosulfite and tetramethylammonium cyanate sulfur dioxide-adduct, [(CH3)(4)N](+)[SO2]N-3](-), [(CH3)(4)N](+)[SO2OCN](-) and crystal structure of [(CH3)(4)N](+)[SO2N3](-) [German] [J] . Kornath A., Blecher O., Ludwig R. Zeitschrift fur Anorganische und Allgemeine Chemie . 2002,第1期

机译：叠氮亚硫酸四甲基铵和氰酸四甲基铵氰酸二氧化硫加合物的制备，[（CH3）（4）N]（+）[SO2] N-3]（-），[（CH3）（4）N]（+）[SO2OCN] （-）和[（CH3）（4）N]（+）[SO2N3]（-）的晶体结构[德语]
3. PREPARATION AND NMR SPECTRA OF THE (TRIFLUOROMETHYL)ARGENTATES(III) [AG(CF3)(N)X(4-N)](-), WITH X=CN (N=1-3), CH3, C=CC6H11, CL, BR (N=2, 3), AND I (N=3), AND OF RELATED SILVER(III) COMPOUNDS - STRUCTURES OF [PPH(4)][TRANS-AG(CF3)(2)(CN)(2)] AND [PPH [J] . Eujen R., Brauer DJ., Hoge B. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第7期

机译：（三氟甲基）（III）[AG（CF3）（N）X（4-N）]（-）的制备和NMR光谱，X = CN（N = 1-3），CH3，C = CC6H11， CL，BR（N = 2、3）和I（N = 3）以及相关的银（III）化合物-[PPH（4）] [TRANS-AG（CF3）（2）（CN）（ 2）]和[PPH

ON THE PREPARATION OF TETRAMETHYLAMMONIUM TRIFLUOROMETHYLBISTRIFLUOROMETHYLNITROXYLIODATE(I) (CH3)(4)N+(CF3)2NOICF(3)(-) AND THE REACTION OF TETRAMETHYLAMMONIUM BISTRIFLUOROMETHYLNITRATE (CH3)(4)N+(CF3)(2)NO- WITH CL-2 AND CLONO2 [German]

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