Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

Robert J. Baker; Cameron Jones; Jamie A. Platts

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Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

机译：铁-镓（I）杂环配合物的合成，结构和理论研究：与N-杂环卡宾化学类似

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The first iron complex of an anionic gallium N-heterocyclic carbene analogue, [Fe(CO)_4{Ga[N(Ar)C(H)]_2}]~- Ar = C_6H_3-Pr_2~i-2,6, has been prepared and shown to have an unusual polymeric structure in the solid state; theoretical studies have pointed toward minimal Fe → Ga back-bonding in this complex.

机译：阴离子镓N杂环卡宾类似物的第一铁配合物[Fe（CO）_4 {Ga [N（Ar）C（H）] _ 2}]〜-Ar = C_6H_3-Pr_2〜i-2,6制备并显示出具有固态的异常聚合物结构;理论研究指出，在这种复合物中，Fe→Ga的最小背键。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第19期|共2页
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Robert J. Baker; Cameron Jones; Jamie A. Platts;
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1. Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry [J] . Robert J. Baker, Cameron Jones, Jamie A. Platts Dalton transactions: An international journal of inorganic chemistry . 2003,第19期

机译：铁-镓（I）杂环配合物的合成，结构和理论研究：与N-杂环卡宾化学类似
2. Synthesis and structural characterization of a [Ag-4](4+) cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water [J] . Garrison JC., Simons RS., Tessier CA., Journal of Organometallic Chemistry . 2003,第1a2期

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3. Iridium(III) N-heterocyclic carbene complexes: an experimental and theoretical study of structural, spectroscopic, electrochemical and electrogenerated chemiluminescence properties [J] . Barbante Gregory J., Doeven Egan H., Francis Paul S., Dalton transactions: An international journal of inorganic chemistry . 2015,第18期

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Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

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