[M(L)(2)(NCS)(2)(H2O)(2)] (M = Mn-II or Co-II and L=2,5-bis(4-pyridyl)-1,3,4-oxadiazole): three-dimensional extended networks built from hydrogen bonds and pi-pi stacking interaction - syntheses and crystal structures

Fang YY.; Liu H.; Du M.; Guo YM.; Bu XH.

首页> 外文期刊>Journal of Molecular Structure >[M(L)(2)(NCS)(2)(H2O)(2)] (M = Mn-II or Co-II and L=2,5-bis(4-pyridyl)-1,3,4-oxadiazole): three-dimensional extended networks built from hydrogen bonds and pi-pi stacking interaction - syntheses and crystal structures

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[M(L)(2)(NCS)(2)(H2O)(2)] (M = Mn-II or Co-II and L=2,5-bis(4-pyridyl)-1,3,4-oxadiazole): three-dimensional extended networks built from hydrogen bonds and pi-pi stacking interaction - syntheses and crystal structures

机译：[M（L）（2）（NCS）（2）（H2O）（2）]（M = Mn-II或Co-II，L = 2,5-双（4-吡啶基）-1,3,4 -恶二唑）：由氢键和pi-pi堆积相互作用构建的三维扩展网络-合成和晶体结构

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Two three-dimensional (3D) supramolecular compounds of the general formula [M(L)(2)(NCS)(2)(H2O)(2)], where M is Mn-II or Co-II and L is 2,5-bis(4-pyridyl)-1,3,4-oxadiazole), have been synthesized and structurally determined by X-ray diffraction analyses. The crystal structures of both complexes reveal that they are isomorphic neutral molecules and the metal ions are at the center of symmetry. Each metal center is six-coordinated and the MN4O2 coordination sphere can be considered as an octahedron. The most striking feature of both complexes resides in the formation of a 3D network through hydrogen bonds and pi-pi stacking co-effection. (C) 2002 Elsevier Science B.V. All rights reserved. [References: 16]

机译：通式为[M（L）（2）（NCS）（2）（H2O）（2）]的两个三维（3D）超分子化合物，其中M为Mn-II或Co-II，L为2，已经合成了5-双（4-吡啶基）-1,3,4-恶二唑，并通过X射线衍射分析确定了结构。两种配合物的晶体结构都表明它们是同构的中性分子，金属离子位于对称中心。每个金属中心都是六坐标的，并且MN4O2的坐标球可以看作是八面体。两种配合物最显着的特征在于通过氢键和pi-pi堆积共效应形成3D网络。（C）2002 Elsevier Science B.V.保留所有权利。 [参考：16]

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《Journal of Molecular Structure》 |2002年第3期|共5页
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Fang YY.; Liu H.; Du M.; Guo YM.; Bu XH.;
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中图分类结构化学;分子结构;
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1. [M(L)(2)(NCS)(2)(H2O)(2)] (M = Mn-II or Co-II and L=2,5-bis(4-pyridyl)-1,3,4-oxadiazole): three-dimensional extended networks built from hydrogen bonds and pi-pi stacking interaction - syntheses and crystal structures [J] . Fang YY., Liu H., Du M., Journal of Molecular Structure . 2002,第2a3期

机译：[M（L）（2）（NCS）（2）（H2O）（2）]（M = Mn-II或Co-II，L = 2,5-双（4-吡啶基）-1,3,4 -恶二唑）：由氢键和pi-pi堆积相互作用构建的三维扩展网络-合成和晶体结构
2. Synthesis, characterization and crystal structures of new Mn-II, Fe-II and Ag-I complexes with an angular dipyridyl ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole [J] . Du M, Zhao XJ Journal of Molecular Structure . 2004,第1a3期

机译：具有角二吡啶基配体2,5-双（4-吡啶基）-1,3,4-恶二唑的新型Mn-II，Fe-II和Ag-I配合物的合成，表征和晶体结构
3. Syntheses, Crystal Structures, and Thermal Stability of Metal-Directed Co(II) and Cu(II) Coordination Assemblies with Mixed Ligands of 5-Methylisophthalic Acid and 2,5-Bis(4-Pyridyl)-1,3,4-Oxadiazole [J] . Shang-Yuan Liu, Cheng-Peng Li Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry . 2011,第6期

机译：含5-甲基间苯二甲酸和2,5-双（4-吡啶基）-1,3,4-Oxadiazole的混合配体的金属定向Co（II）和Cu（II）配位化合物的合成，晶体结构和热稳定性
4. The Synthesis, Crystal Structure and Self-Organization of Molecules Containing 2,5-Bis(o-amino-phenyi)-1,3,4-Oxadiazoles Unit and N-Tos-L-Amino Acid Residues [C] . Hongwu Zhao International symposium for Chinese organic chemists . 2000

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5. The crystal structure of 1-(2-iodobenzoyl)-4-(pyrimidin-2-yl)piperazine: a three-dimensional hydrogen-bonded framework augmented by π–π stacking interactions and I⋯N halogen bonds [O] . Ninganayaka Mahesha, Hemmige S. Yathirajan, Tetsundo Furuya, 2019

机译：1-（2-碘苯并基）-4-（嘧啶-2-基）哌嗪的晶体结构：三维氢键骨架并通过π-π堆积相互作用和I⋯N卤素键增强
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机译：4-溴-β-（2-氧代喹啉-4-基氧基）肉桂腈：由NH中心点中心点中心点O和CH中心点中心点中心点O的氢键，溴代羰基和芳香pi-pi堆积相互作用

[M(L)(2)(NCS)(2)(H2O)(2)] (M = Mn-II or Co-II and L=2,5-bis(4-pyridyl)-1,3,4-oxadiazole): three-dimensional extended networks built from hydrogen bonds and pi-pi stacking interaction - syntheses and crystal structures

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