Enantioselective photochromism of diarylethenes in human serum albumin

Fukagawa M.; Kawamura I.; Ubukata T.; Yokoyama Y.

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Enantioselective photochromism of diarylethenes in human serum albumin

机译：人血清白蛋白中二芳烃的对映选择性光致变色

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Making light work of chromism: Enantioselective photochromic ring-closing reactions of three bisthienylethene compounds possessing either no or two hydroxy groups were carried out in the hydrophobic pockets of human serum albumin (HSA) in aqueous media. When 10 equivalents of HSA were used, 1,2-bis(5-hydroxymethyl-2-methyl-3-thienyl)hexafluorocyclopentene predominantly produced the S,S closed form (see scheme; O=open, C=closed), in 63 % ee at RT and 71 % ee at -4°C upon irradiation with 313 nm light.

机译：使变色作用发挥作用：在水性介质中人血清白蛋白（HSA）的疏水口袋中，进行了三种不具有或不具有两个羟基的联苯撑乙烯基化合物的对映选择性光致变色闭环反应。当使用10当量的HSA时，63中的1,2-双（5-羟甲基-2-甲基-3-噻吩基）六氟环戊烯主要生成S，S封闭形式（参见方案; O =开放，C =封闭）。在用313 nm的光照射时，室温下的ee百分数为-4，而在-4°C的百分数为ee的百分数。

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《Chemistry: A European journal》 |2013年第29期|共4页
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Fukagawa M.; Kawamura I.; Ubukata T.; Yokoyama Y.;
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正文语种 eng
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chirality transfer; diarylethenes; enantioselectivity; human serum albumin; photochromism;

机译：手性转移二芳烃对映选择性人血清白蛋白光致变色;

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1. Enantioselective photochromism of diarylethenes in human serum albumin [J] . Fukagawa M., Kawamura I., Ubukata T., Chemistry: A European journal . 2013,第29期

机译：人血清白蛋白中二芳烃的对映选择性光致变色
2. Affinity capillary electrophoresis and fluorescence spectroscopy for studying enantioselective interactions between omeprazole enantiomer and human serum albumin [J] . Xu Yujing, Hong Tingting, Chen Xueping, Electrophoresis: The Official Journal of the International Electrophoresis Society . 2017,第9a10期

机译：亲和毛细管电泳和荧光光谱研究奥美拉唑对映体与人血清白蛋白的映选择性相互作用
3. Chiral Derivatives of Xanthones: Investigation of the Effect of Enantioselectivity on Inhibition of Cyclooxygenases (COX-1 and COX-2) and Binding Interaction with Human Serum Albumin [J] . Carla Fernandes, Andreia Palmeira, Inês I. Ramos, Pharmaceuticals . 2017,第2期

机译：氧杂蒽酮的手性衍生物：对映选择性对环氧合酶（COX-1和COX-2）抑制和与人血清白蛋白结合相互作用的影响的研究
4. Comparison of human serum and bovine serum albumins on oxidation dynamics induced by talaporfin sodium photosensitization reaction with albumin rich conditions: solution experiments [C] . Mariko. Kurotsu, Tetsuya. Nakamura, Mei. Takahashi, Optical interactions with tissue and cells XXV; and Terahertz for Biomedical Applications . 2014

机译：富白蛋白条件下人血清和牛血清白蛋白对他拉泊芬钠光敏反应诱导的氧化动力学的比较：
5. Adsorption of biopolymers human serum albumin and human gamma globulin to well-defined surfaces of self-assembled monolayers. [D] . Cregger, Tricia Ann. 2002

机译：生物聚合物人血清白蛋白和人γ球蛋白吸附到自组装单分子层的明确表面上。
6. Chiral Derivatives of Xanthones: Investigation of the Effect of Enantioselectivity on Inhibition of Cyclooxygenases (COX-1 and COX-2) and Binding Interaction with Human Serum Albumin [O] . Carla Fernandes, Andreia Palmeira, Inês I. Ramos, 2017

机译：氧杂蒽酮的手性衍生物：对映选择性对环氧合酶（COX-1和COX-2）的抑制作用以及与人血清白蛋白结合相互作用的影响研究
7. Chiral Derivatives of Xanthones: Investigation of the Effect of Enantioselectivity on Inhibition of Cyclooxygenases (COX-1 and COX-2) and Binding Interaction with Human Serum Albumin [O] . Carla Fernandes, Andreia Palmeira, Inês I. Ramos, 2017

机译：Xanthones的手性衍生物：对映选择性对环氧合酶（COX-1和COX-2）抑制作用及与人血清白蛋白结合相互作用的研究
8. Inhibition of Human Peptidyl Dipeptidase (Angiotensin I Converting Enzyme: Kininase II) by Human Serum Albumin and Its Fragments [R] . Klauser, R. J., Robinson, C. J. G., Marinkovic, D. V., 1979

机译：人血清白蛋白及其片段对人肽基二肽酶（血管紧张素转换酶：激酶II）的抑制作用

Enantioselective photochromism of diarylethenes in human serum albumin

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