ICl-Induced Intramolecular Electrophilic Cyclization of 1-[4'-Methoxy(1,1'- biphenyl)2-yl]alkynones-A Facile Approach to Spiroconjugated Molecules

Yu Chen; Xiaochen Liu; Minwook Lee; Chenlong Huang; Igor Inoyatov; Zhiwei Chen; Abraham C. Perl; William H. Hersh

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ICl-Induced Intramolecular Electrophilic Cyclization of 1-[4'-Methoxy(1,1'- biphenyl)2-yl]alkynones-A Facile Approach to Spiroconjugated Molecules

机译：ICl诱导的1- [4'-甲氧基（1,1'-联苯）2-基]炔酮的分子内亲电环化-螺旋共轭分子的简便方法

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Electrophilic cyclization of functionalized alkynes, induced by halogens and their derivatives, has emerged as an extremely active field in the past decade. This synthetic method provides a facile approach for the synthesis of a variety of functionally substituted heterocyclic and carbocyclic compounds.~([1]) Among the various halogen-induced electrophilic cyclization reactions discovered thus far, limited examples of the intramolecular ipso-cyclization of an alkyne into spiro compounds have been reported, and even fewer have yielded spiroconjugated species.~([2])

机译：在过去的十年中，由卤素及其衍生物诱导的官能化炔烃的亲电环化已经成为一个非常活跃的领域。这种合成方法为合成各种功能取代的杂环和碳环化合物提供了一种简便的方法。[[1]]到目前为止，在发现的各种卤素诱导的亲电环化反应中，分子内ipso环化的有限实例有报道称炔烃可以合成螺环化合物，甚至很少有螺环共轭物。〜[[2]）

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《Chemistry: A European journal》 |2013年第30期|共5页
作者
Yu Chen; Xiaochen Liu; Minwook Lee; Chenlong Huang; Igor Inoyatov; Zhiwei Chen; Abraham C. Perl; William H. Hersh;
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正文语种 eng
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ICl-Induced; Cyclization; Molecules;

机译：ICl诱导;环化;分子;

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1. ICl-Induced Intramolecular Electrophilic Cyclization of 1-[4'-Methoxy(1,1'- biphenyl)2-yl]alkynones-A Facile Approach to Spiroconjugated Molecules [J] . Yu Chen, Xiaochen Liu, Minwook Lee, Chemistry: A European journal . 2013,第30期

机译：ICl诱导的1- [4'-甲氧基（1,1'-联苯）2-基]炔酮的分子内亲电环化-螺旋共轭分子的简便方法
2. Synthesis and Optical Resolution of 1-[(3-Carboxy-1,1 '-biphenyl)-2-yl]-1H-pyrrole-2-carboxylic Acid [J] . Faigl F, Vas-Feldhoffer B, Kudar V, Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2009,第10期

机译：1-[（3-羧基-1,1'-联苯）-2-基] -1H-吡咯-2-羧酸的合成及光学拆分
3. A Facile Synthesis of 5-(4'-substituted)-[1,1'-biphenyl]-2-yl)-1H-tetrazole: A Key Intermediate for Synthesis of Angiotensin II Receptor Antagonist [J] . Reddy Kesamreddy Ranga, Reddy Emani Vijayabhaskar, Kumar J. V. Shanmukha Indian Journal of Heterocyclic Chemistry. (Text in English) . 2018,第2期

机译：容易合成5-（4'-取代的） - [1,1'-联苯] -2-基）-1H-四唑：用于合成血管紧张素II受体拮抗剂的关键中间体
4. Rational design of a (S)-selective-Transaminase for asymmetric synthesis of (1S)-1-(1,1'-biphenyl 2-yl)ethanamine [O] . Dourado Daniel F. A. R., Pohle Stefan, Carvalho Alexandra T. P., 2016

机译：用于（1S）-1-（1,1'-联苯-2-基）乙胺的不对称合成的（S）-选择性转氨酶的合理设计

ICl-Induced Intramolecular Electrophilic Cyclization of 1-[4'-Methoxy(1,1'- biphenyl)2-yl]alkynones-A Facile Approach to Spiroconjugated Molecules

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