ZnO-NP assisted synthesis of fluorescent beta-carboline C-1 tethered benzimidazole/benzothiazole/benzoxazole derivatives and assessment of their photophysical properties

Kumar Vipin; Singh Dharmender; Paul Avijit Kumar; Shrivastava Rahul; Singh Virender

首页> 外文期刊>New Journal of Chemistry >ZnO-NP assisted synthesis of fluorescent beta-carboline C-1 tethered benzimidazole/benzothiazole/benzoxazole derivatives and assessment of their photophysical properties

【24h】

ZnO-NP assisted synthesis of fluorescent beta-carboline C-1 tethered benzimidazole/benzothiazole/benzoxazole derivatives and assessment of their photophysical properties

机译：荧光β-咔啉C-1型苯并咪唑/苯并噻唑/苯并恶唑衍生物的辅助合成及其光学性质的评估

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A facile transformation of 1-formyl beta-carboline into fluorescent beta-carboline C-1 tethered benzazole derivatives is described under the catalysis of ZnO nanoparticles. The reaction proceeded with the reaction of 1-formyl beta-carboline and substituted o-diaminobenzene/2-aminobenzenethiol/2-aminophenol, which results in formation of a Schiff base, followed by an intramolecular cylization reaction to generate beta-carboline linked benzimidazole, benzothiazole and benzoxazole derivatives. This appraoch displayed a wide substrate scope and high regioselectivity to yield the desired products in moderate to good yields. The photophysical properties of the synthesized derivatives were also evaluated and they exhibited excellent fluorescence properties. Among these beta-carboline substituted azoles, the benzothiazole derivative displayed the maximum quantum yield (phi(F) up to 28%).

机译：在ZnO纳米颗粒的催化下描述了1-甲酰β-咔啉的1-甲酰β-咔啉C-1型苯并吡唑衍生物的容纳转化。反应采用1-甲酰基β-咔啉和取代的O-二氨基苯/ 2-氨基苯酚/ 2-氨基苯酚的反应进行，这导致形成Schiff碱，其次是分子内圆柱形反应，以产生β-咔啉连接苯并咪唑，苯并噻唑和苯并恶唑衍生物。该估算量展示了宽的基底范围和高区域选择性，以产生中等至良好产量的所需产物。还评估了合成衍生物的光物理性质，并且它们表现出优异的荧光性质。在这些β-咔啉取代的唑胺中，苯并噻唑衍生物显示最大量子产率（PHI（F）至28％）。

著录项

来源
《New Journal of Chemistry》 |2019年第46期|共12页
作者
Kumar Vipin; Singh Dharmender; Paul Avijit Kumar; Shrivastava Rahul; Singh Virender;
展开▼
作者单位

Dr BR Ambedkar Natl Inst Technol NIT Dept Chem Jalandhar 144011 Punjab India;

Dr BR Ambedkar Natl Inst Technol NIT Dept Chem Jalandhar 144011 Punjab India;

NIT Dept Chem Kurukshetra 136119 Haryana India;

Manipal Univ Jaipur Dept Chem Jaipur 303007 Rajasthan India;

Dr BR Ambedkar Natl Inst Technol NIT Dept Chem Jalandhar 144011 Punjab India;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. ZnO-NP assisted synthesis of fluorescent beta-carboline C-1 tethered benzimidazole/benzothiazole/benzoxazole derivatives and assessment of their photophysical properties [J] . Kumar Vipin, Singh Dharmender, Paul Avijit Kumar, New Journal of Chemistry . 2019,第46期

机译：荧光β-咔啉C-1型苯并咪唑/苯并噻唑/苯并恶唑衍生物的辅助合成及其光学性质的评估
2. Synthesis and Photo-Physical Characteristics of ESIPT Inspired 2-Substituted Benzimidazole, Benzoxazole and Benzothiazole Fluorescent Derivatives [J] . Journal of Fluorescence . 2012,第1期

机译：ESIPT启发的2-取代苯并咪唑，苯并恶唑和苯并噻唑荧光衍生物的合成及光物理特性
3. Microwave assisted one pot synthesis of 2-ethylamino benzimidazole, benzoxazole and benzothiazole derivatives [J] . Rapolu Thirupathi, Kumar Pavan K. V. P., Babu Korupolu Raghu, Synthetic Communications . 2019,第9a12期

机译：微波炉辅助1罐合成2-乙基氨基苯并咪唑，苯并恶唑和苯并噻唑衍生物
4. Synthesis and Photophysical Properties of Red-emitting Iridium (III) Complex Bearing Benzothiazole [C] . XIAO Guoyong, LI Xiao, CHI Haijun, International Conference on Chemical, Material and Metallurgical Engineering . 2012

机译：红发射铱（III）复合物轴承苯并噻唑的合成和光学性质
5. Synthesis and Characterization of Novel Fluorescent Sensors Based on Terpyridine, Benzoxazole and Benzothiazole Chromophores [D] . Bi, Xiaoman. 2017

机译：基于联吡啶，苯并恶唑和苯并噻唑发色团的新型荧光传感器的合成与表征
6. Novel Benzothiazole Benzimidazole and Benzoxazole Derivatives as Potential Antitumor Agents: Synthesis and Preliminary in Vitro Biological Evaluation [O] . Pu Xiang, Tian Zhou, Liang Wang, 2012

机译：新型苯并噻唑苯并咪唑和苯并恶唑衍生物作为潜在的抗肿瘤剂：合成及体外生物学评估
7. Synthesis of novel dipodal-benzimidazole, benzoxazole and benzothiazole from cyanuric chloride: Structural, photophysical and antimicrobial studies [O] . Padalkar Vikas S., Gupta Vinod D., Phatangare Kiran R., 2014

机译：氰尿酰氯合成新型二足苯并咪唑，苯并恶唑和苯并噻唑的结构，光物理和抗菌研究
8. Synthesis and Evaluation of Third-Order Optical Nonlinearities of Model CompoundsContaining Benzothiazole, Benzimidazole and Benzoxazole Moieties [R] . Reinhardt, B. A., Unroe, M. R., Prazak, M., 1991

机译：含有苯并噻唑，苯并咪唑和苯并恶唑的模型化合物的三阶光学非线性的合成与评价

ZnO-NP assisted synthesis of fluorescent beta-carboline C-1 tethered benzimidazole/benzothiazole/benzoxazole derivatives and assessment of their photophysical properties

摘要

著录项

相似文献

相关主题

期刊订阅