The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

Khavasi Hamid Reza; Ghanbarpour Alireza; Tehrani Alireza Azhdari

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The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

机译：涉及卤素的分子间相互作用在一系列Mn（II）配位化合物的超分子结构中的作用

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A series of four new manganese(II) complexes based on the L4-X ligand, where L is N-(4-halo)phenyl picolinamide ligands, have been synthesized, characterized and their supramolecular crystal structures were studied by geometrical analysis and theoretical calculation. Our study reveals the role of weak intermolecular interactions involving halogens, such as C-H center dot center dot center dot X hydrogen bonds (in the cases of 1 and 2) and C-X center dot center dot center dot X'-M halogen bonds (in the cases of 3 and 4), in the structural changes of supramolecular assemblies of coordination compounds. This study could provide further insight into discovering the role of weak intermolecular interactions in the context of metallosupramolecular assembly.

机译：基于L4-X配体的一系列四种新的锰（II）配合物，其中L是N-（4-卤素）苯基吡啶胺酰胺配体，其特征在于，通过几何分析和理论计算研究了它们的超分子晶体结构。我们的研究揭示了涉及卤素的弱分子间相互作用的作用，例如CH中心点中心点中心点X氢键（在1和2的情况下）和CX中心点中心点中心点X'-M卤素键（在 3和4），在配位化合物的超分子组件的结构变化中。本研究可以进一步了解发现在Metallosupramular集装的背景下的分子间相互作用弱分子间相互作用。

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《RSC Advances》 |2016年第3期|共9页
作者
Khavasi Hamid Reza; Ghanbarpour Alireza; Tehrani Alireza Azhdari;
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Shahid Beheshti Univ Fac Chem Tehran 1983963113 Iran;

Shahid Beheshti Univ Fac Chem Tehran 1983963113 Iran;

Shahid Beheshti Univ Fac Chem Tehran 1983963113 Iran;

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1. The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds [J] . Khavasi Hamid Reza, Ghanbarpour Alireza, Tehrani Alireza Azhdari RSC Advances . 2016,第3期

机译：涉及卤素的分子间相互作用在一系列Mn（II）配位化合物的超分子结构中的作用
2. Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [Mn~(III)L(OH)2Li~I]_n through both intermolecular hydrogen bonds and π-π stacking interactions [J] . Wen-Kui Dong, Chun-Yu Zhao, Yin-Xia Sun Inorganic Chemistry Communications . 2009,第3期

机译：通过分子间氢键和π-π堆积相互作用的空前超分子桥连式羟基锰（III）-锂（I）配位聚合物[Mn〜（III）L（OH）2Li〜I] _n的合成与结构
3. Antiproliferative evaluation and supramolecular association involving electrostatically enhanced pi-pi interaction in isostructural coordination solids of Mn(II), Co(II) and Zn(II) chlorobenzoates: Experimental and theoretical studies [J] . Nashre-ul-Islam Swah Mohd, Dutta Debajit, Verma Akalesh K., Inorganica Chimica Acta . 2019,第期

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4. Theoretical investigations of intermolecular interactions involving π-systems and their utility in the design of novel functional nanomaterials [C] . Nanotechnology conference and trade show . 2003

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5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

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6. Importance of halide involving interactions at Hoogsteen sites in supramolecular architectures of some coordination metal complexes of N6-benzyl/furfuryl adenine [O] . Samson Jegan Jennifer, Packianathan Thomas Muthiah, Duraiswamy Tamilselvi 2014

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7. Weak intermolecular hydrogen and halogen interactions in an isomorphous halogen series of pseudoterpyridine Zn II complexes [O] . Dumitru Florina, Legrand Yves-Marie, Barboiu Mihail, 2013

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8. CATALOG OF NUCLEAR QUADRUPOLE INTERACTIONS AND RESONANCE FREQUENCIES IN SOLIDS. PART II. HALOGEN RESONANCES IN ORGANIC COMPOUNDS [R] . S. L. Segel, R. G. Barnes 1965

机译：固体中核四极相互作用和共振频率的目录。第二部分。有机化合物中的卤素共振

The role of intermolecular interactions involving halogens in the supramolecular architecture of a series of Mn(II) coordination compounds

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